Rule 8.3 - RIO TINTO PLC

FORM 8.3 DEALINGS BY PERSONS WITH INTERESTS IN SECURITIES REPRESENTING 1% OR MORE (Rule 8.3 of the City Code on Takeovers and Mergers) 1. KEY INFORMATION Name of person dealing BARCLAYS PLC (Note 1) Company dealt in RIO TINTO Class of relevant security ORD GBP0.10 to which the dealings being disclosed relate (Note 2) Date of dealing 18 September 2008 2. INTERESTS, SHORT POSITIONS AND RIGHTS TO SUBSCRIBE (a) Interests and short positions (following dealing) in the class of relevant security dealt in (Note 3) Long Short Number (%) Number (%) (1) Relevant 46,872,642 4.68% 612,001 0.06% securities (2) Derivatives 524,363 0.05% 2,068,948 0.21% (other than options) (3) Options and 101,200 0.01% 151,400 0.02% agreements to purchase/sell Total 47,498,205 4.74% 2,832,349 0.28% (b) Interests and short positions in relevant securities of the company, other than the class dealt in (Note 3) Class of Long Short relevant security: Number (%) Number (%) (1) Relevant securities (2) Derivatives (other than options) (3) Options and agreements to purchase/sell Total (c) Rights to subscribe (Note 3) Class of relevant security: Details 3. DEALINGS (Note 4) (a) Purchases and sales Purchase/sale Number of Securities Price per unit (GBP) Purchase 2,000 37.7704 Purchase 52,990 37.1545 Purchase 11,500 36.4914 Purchase 3,106 36.5500 Purchase 13,625 37.4331 Purchase 70,271 36.7841 Purchase 10,000 37.6492 Purchase 87 Transfer Purchase 98,880 36.5000 Purchase 48,632 37.1785 Purchase 16,735 36.5500 Purchase 2,139 37.9389 Purchase 850 36.5500 Purchase 115 37.6157 Purchase 13,000 36.5500 Purchase 8,300 37.1101 Purchase 33,433 37.0630 Purchase 54 Transfer Purchase 3,068 37.2304 Sale 61,200 37.5826 Sale 103 37.3550 Sale 46 40.7130 Sale 843 Transfer Sale 67,639 37.6772 Sale 437 Transfer Sale 255 38.2600 Sale 642 65.4000 USD Sale 54 Transfer Sale 13,000 36.0000 Sale 34 41.3230 Sale 120 65.4000 USD Sale 1,650 37.4540 Sale 87 Transfer Sale 1,280 37.3197 Sale 140 37.7800 Sale 349 38.2600 Sale 47 Transfer Sale 1,016 37.6331 Sale 2,252 37.6331 Sale 200 38.0130 Sale 377 36.5500 Sale 1,672 36.5500 Sale 600 37.1500 Sale 953 Transfer Sale 160 37.7800 Sale 147 Transfer Sale 17,103 36.5500 Sale 90 37.7800 Sale 50 38.3576 Sale 28,174 37.3935 Sale 13,600 37.4672 Sale 11,963 37.7902 Sale 8,073 39.4454 Sale 16,642 37.2571 Sale 3,068 37.2304 Sale 150 37.7800 NB: The below transactions which were previously disclosed have been cancelled Deal Date Purchase/Sale Number of Securities Price per unit (GBP) 17/09/2008 Sale 243 40.3300 (b) Derivatives transactions (other than options) Product name, Long/Short Number of Price per (e.g. CFD) (Note 6) Securities unit (GBP) CFD Long 16642 37.257 CFD Long 1280 37.3197 CFD Long 19031 37.3855 CFD Long 13600 37.4671 CFD Long 61200 37.5825 CFD Long 67639 37.6772 CFD Long 11963 37.7901 CFD Short 11500 36.4914 CFD Short 4205 36.55 CFD Short 70271 36.784 CFD Short 33433 37.0629 CFD Short 8300 37.1101 CFD Short 52990 37.1544 CFD Short 48632 37.1784 CFD Short 115 37.6156 CFD Short 10000 37.6492 CFD Short 2000 37.7704 (c) Options transactions in respect of existing securities (i) Writing, selling, purchasing or varying Product name, Writing, Number of Exercise Type, e.g. Expiry Option money e.g. call selling, securities to price American, date paid/received option purchasing, which the option European etc. per unit (GBP) varying etc. relates (GBP) (ii) Exercising Product name, e.g. Number of Exercise price per call option securities unit (Note 5) (d) Other dealings (including new securities) (Note 4) Nature of transaction Details Price per unit (Note 8) (if applicable) (Note 5) 4. OTHER INFORMATION None Agreements, arrangements or understandings relating to options or derivatives Full details of any agreement, arrangement or understanding between the person disclosing and any other person relating to the voting rights of any relevant securities under any option referred to on this form or relating to the voting rights or future acquisition or disposal of any relevant securities to which any derivative referred to on this form is referenced. If none, this should be stated. Is a Supplemental Form 8 attached? (Note 9) YES Date of disclosure 19 September 2008 Contact name Geoff Smith Telephone number 020 7116 2913 If a connected EFM, name of offeree/offeror with which connected If a connected EFM, state nature of connection (Note 10) Notes The Notes on Form 8.3 can be viewed on the Takeover Panel's website at www.thetakeoverpanel.org.uk SUPPLEMENTAL FORM 8 DETAILS OF OPEN POSITIONS (This form should be attached to Form 8.1, Form 8.1(b)(ii) or Form 8.3, as appropriate) OPEN POSITIONS (Note 1) Product name, Written or Number of securities Exercise price Type, e.g. Expiry date e.g. call option purchased to which the option (Note 2) American, or derivative relates European etc. Option Purchased 100,000 56.0000 AMER 18/12/2009 Option Purchased -50,000 64.0000 AMER 21/11/2008 Option Purchased -100,000 64.0000 AMER 21/11/2008 Option Purchased 500 5,000.0000 EURO 19/12/2008 Option Purchased 350 4,600.0000 EURO 19/12/2008 Option Purchased 350 4,600.0000 EURO 19/12/2008 Option Purchased -135 5,200.0000 EURO 19/12/2008 Option Purchased -145 5,200.0000 EURO 19/12/2008 Option Purchased -270 6,400.0000 EURO 19/12/2008 Option Purchased -350 5,000.0000 EURO 19/12/2008 Option Purchased -500 7,000.0000 EURO 19/12/2008 Notes 1. Where there are open option positions or open derivative positions (except for CFDs), full details should be given. Full details of any existing agreements to purchase or to sell should also be given on this form. 2. For all prices and other monetary amounts, the currency must be stated. For details of the Code's dealing disclosure requirements, see Rule 8 and its Notes which can be viewed on the Takeover Panel's website at www.thetakeoverpanel.org.uk

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Barclays (BARC)
UK 100

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