Rule 8.3 - RIO TINTO PLC

FORM 8.3 DEALINGS BY PERSONS WITH INTERESTS IN SECURITIES REPRESENTING 1% OR MORE (Rule 8.3 of the City Code on Takeovers and Mergers) 1. KEY INFORMATION Name of person dealing BARCLAYS PLC (Note 1) Company dealt in RIO TINTO Class of relevant security ORD GBP0.10 to which the dealings being disclosed relate (Note 2) Date of dealing 23 September 2008 2. INTERESTS, SHORT POSITIONS AND RIGHTS TO SUBSCRIBE (a) Interests and short positions (following dealing) in the class of relevant security dealt in (Note 3) Long Short Number (%) Number (%) (1) Relevant 46,596,675 4.67% 598,883 0.06% securities (2) Derivatives 786,010 0.08% 1,755,917 0.18% (other than options) (3) Options and 101,200 0.01% 151,400 0.02% agreements to purchase/sell Total 47,483,885 4.76% 2,506,200 0.25% (b) Interests and short positions in relevant securities of the company, other than the class dealt in (Note 3) Class of Long Short relevant security: Number (%) Number (%) (1) Relevant securities (2) Derivatives (other than options) (3) Options and agreements to purchase/sell Total (c) Rights to subscribe (Note 3) Class of relevant security: Details 3. DEALINGS (Note 4) (a) Purchases and sales Purchase/sale Number of Securities Price per unit (GBP) Purchase 20 40.4055 Purchase 1,253 40.4554 Purchase 41,901 42.4000 Purchase 22,278 40.3072 Purchase 55,855 40.5564 Purchase 99 Transfer Purchase 12,209 40.3158 Purchase 713 40.3934 Purchase 77,274 40.3950 Purchase 25,534 40.2797 Purchase 1,323 40.4175 Purchase 390 44.5628 Purchase 2,574 40.1753 Purchase 39,000 40.2300 Purchase 3,826 40.2598 Purchase 6,523 42.4000 Purchase 271 40.4149 Purchase 26,656 42.4000 Purchase 16,660 40.2300 Purchase 200 40.3300 Sale 6,008 40.4670 Sale 71 Transfer Sale 22,726 40.8139 Sale 200 40.3300 Sale 41,901 42.4000 Sale 1,760 40.4491 Sale 99 Transfer Sale 50,423 40.5489 Sale 1,200 40.7047 Sale 77,274 40.3950 Sale 390 44.5628 Sale 89 42.0870 Sale 25,019 43.8379 Sale 777 40.2300 Sale 3,429 40.2300 Sale 77,274 40.3950 Sale 6,523 42.4000 Sale 824 42.4000 Sale 328 40.4165 Sale 166 40.4164 Sale 71 41.3000 Sale 200 39.9700 Sale 485 Transfer Sale 153 40.5151 Sale 8,652 40.5056 Sale 28,756 40.2300 Sale 10,313 40.4130 Sale 390 40.0400 Sale 73,885 40.3683 Sale 16,900 40.5763 Sale 23,761 40.5828 Sale 6 42.6300 Sale 5,602 40.3317 Sale 816 40.5151 (b) Derivatives transactions (other than options) Product name, Long/Short Number of Price per (e.g. CFD) (Note 6) Securities unit (GBP) CFD Long 200 40.33 CFD Long 73885 40.3682 CFD Long 10313 40.413 CFD Long 1760 40.449 CFD Long 6008 40.467 CFD Long 8652 40.5055 CFD Long 50423 40.5488 CFD Long 16900 40.5763 CFD Long 23761 40.5828 CFD Long 1200 40.7047 CFD Long 22726 40.8138 CFD Long 25019 43.8379 CFD Short 3826 40.2597 CFD Short 25534 40.2797 CFD Short 22278 40.3072 CFD Short 12209 40.3158 CFD Short 200 40.33 CFD Short 20 40.4055 CFD Short 55855 40.5563 (c) Options transactions in respect of existing securities (i) Writing, selling, purchasing or varying Product name, Writing, Number of Exercise Type, e.g. Expiry Option money e.g. call selling, securities to price American, date paid/received option purchasing, which the option European etc. per unit (GBP) varying etc. relates (GBP) (ii) Exercising Product name, e.g. Number of Exercise price per call option securities unit (Note 5) (d) Other dealings (including new securities) (Note 4) Nature of transaction Details Price per unit (Note 8) (if applicable) (Note 5) 4. OTHER INFORMATION None Agreements, arrangements or understandings relating to options or derivatives Full details of any agreement, arrangement or understanding between the person disclosing and any other person relating to the voting rights of any relevant securities under any option referred to on this form or relating to the voting rights or future acquisition or disposal of any relevant securities to which any derivative referred to on this form is referenced. If none, this should be stated. Is a Supplemental Form 8 attached? (Note 9) YES Date of disclosure 24 September 2008 Contact name Geoff Smith Telephone number 020 7116 2913 If a connected EFM, name of offeree/offeror with which connected If a connected EFM, state nature of connection (Note 10) Notes The Notes on Form 8.3 can be viewed on the Takeover Panel's website at www.thetakeoverpanel.org.uk SUPPLEMENTAL FORM 8 DETAILS OF OPEN POSITIONS (This form should be attached to Form 8.1, Form 8.1(b)(ii) or Form 8.3, as appropriate) OPEN POSITIONS (Note 1) Product name, Written or Number of securities Exercise price Type, e.g. Expiry date e.g. call option purchased to which the option (Note 2) American, or derivative relates European etc. Option Purchased 100,000 56.0000 AMER 18/12/2009 Option Purchased -50,000 64.0000 AMER 21/11/2008 Option Purchased -100,000 64.0000 AMER 21/11/2008 Option Purchased 500 5,000.0000 EURO 19/12/2008 Option Purchased 350 4,600.0000 EURO 19/12/2008 Option Purchased 350 4,600.0000 EURO 19/12/2008 Option Purchased -135 5,200.0000 EURO 19/12/2008 Option Purchased -145 5,200.0000 EURO 19/12/2008 Option Purchased -270 6,400.0000 EURO 19/12/2008 Option Purchased -350 5,000.0000 EURO 19/12/2008 Option Purchased -500 7,000.0000 EURO 19/12/2008 Notes 1. Where there are open option positions or open derivative positions (except for CFDs), full details should be given. Full details of any existing agreements to purchase or to sell should also be given on this form. 2. For all prices and other monetary amounts, the currency must be stated. For details of the Code's dealing disclosure requirements, see Rule 8 and its Notes which can be viewed on the Takeover Panel's website at www.thetakeoverpanel.org.uk

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Barclays (BARC)
UK 100

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