Rule 8.3 - RIO TINTO PLC

FORM 8.3 DEALINGS BY PERSONS WITH INTERESTS IN SECURITIES REPRESENTING 1% OR MORE (Rule 8.3 of the City Code on Takeovers and Mergers) 1. KEY INFORMATION Name of person dealing BARCLAYS PLC (Note 1) Company dealt in RIO TINTO Class of relevant security ORD GBP0.10 to which the dealings being disclosed relate (Note 2) Date of dealing 13 October 2008 2. INTERESTS, SHORT POSITIONS AND RIGHTS TO SUBSCRIBE (a) Interests and short positions (following dealing) in the class of relevant security dealt in (Note 3) Long Short Number (%) Number (%) (1) Relevant 46,957,242 4.70% 783,413 0.08% securities (2) Derivatives 1,037,562 0.10% 1,702,394 0.17% (other than options) (3) Options and 101,200 0.01% 276,980 0.03% agreements to purchase/sell Total 48,096,004 4.82% 2,762,787 0.28% (b) Interests and short positions in relevant securities of the company, other than the class dealt in (Note 3) Class of Long Short relevant security: Number (%) Number (%) (1) Relevant securities (2) Derivatives (other than options) (3) Options and agreements to purchase/sell Total (c) Rights to subscribe (Note 3) Class of relevant security: Details 3. DEALINGS (Note 4) (a) Purchases and sales Purchase/sale Number of Securities Price per unit (GBP) Purchase 18,855 27.1581 Purchase 31,412 26.7663 Purchase 4,564 27.9700 Purchase 17 Transfer Purchase 2,282 27.9700 Purchase 5,817 27.9700 Purchase 4,986 27.9700 Purchase 4,824 27.9700 Purchase 663 23.9900 Purchase 13,215 23.8125 Purchase 1,444 26.8004 Purchase 995 27.0979 Purchase 200 33.8400 EUR Purchase 75 26.8500 Purchase 1,651 27.3033 Purchase 3,076 26.7722 Purchase 12,328 24.6277 Purchase 1,192 26.7722 Purchase 8,200 26.7119 Purchase 24 Transfer Purchase 3,518 27.7998 Purchase 35 26.6800 Purchase 838 26.4715 Purchase 9,079 27.7998 Purchase 29,800 27.7220 Purchase 33,885 26.7353 Purchase 2,035 25.5043 Purchase 7,067 27.9700 Purchase 2,734 27.7998 Purchase 1,430 26.1798 Purchase 12,000 27.9700 Purchase 90 24.2400 Purchase 5,705 27.9700 Purchase 1,500 26.3253 Purchase 7,739 27.6320 Purchase 926 26.7722 Purchase 1,898 26.1361 Purchase 2,035 25.5043 Purchase 18,000 52.0000 Purchase 61 26.6744 Purchase 18,000 52.0000 Purchase 6,308 26.1361 Purchase 64,248 24.5968 Purchase 1,723 27.9700 Purchase 3 Transfer Sale 67 25.4700 Sale 101 25.4700 Sale 61 25.4700 Sale 16,907 26.6828 Sale 19,948 26.4310 Sale 795 25.4700 Sale 72 25.4700 Sale 22 25.3100 Sale 1,000 40.4800 USD Sale 7,067 27.9959 Sale 87 25.4700 Sale 50,070 27.9700 Sale 508 26.2200 Sale 89 25.4700 Sale 61 25.4700 Sale 80 25.4700 Sale 130 25.4700 Sale 61 25.4700 Sale 95 25.4700 Sale 68 25.4700 Sale 110 25.4700 Sale 447 27.9700 Sale 118 25.4700 Sale 180 25.4700 Sale 125 25.4700 Sale 36,113 26.4942 Sale 90 25.4700 Sale 2,383 27.9700 Sale 155,151 26.9257 Sale 38 26.3000 Sale 200 24.2800 Sale 4,200 26.3912 Sale 77,800 27.6211 Sale 1,700 26.7745 Sale 28 Transfer Sale 61 23.9600 Sale 64 25.4700 Sale 37 23.9500 Sale 425 27.9700 Sale 198 26.3000 Sale 29 24.1500 Sale 1,500 27.9954 Sale 120 27.5400 Sale 58 Transfer Sale 18,000 52.0000 Sale 25 23.9500 Sale 90 24.2400 Sale 110 25.4700 Sale 22,800 26.6523 Sale 125 25.4700 Sale 28,341 26.7467 Sale 163,182 26.4463 Sale 25 24.5700 Sale 120 25.4700 Sale 150 26.6200 Sale 28 Transfer Sale 190 25.4700 Sale 5,075 26.7000 Sale 95 25.4700 Sale 90 25.4700 Sale 40 27.0800 Sale 60 27.0800 Sale 79 25.4700 Sale 83 25.4700 Sale 90 34.7800 EUR Sale 320,451 24.6892 Sale 390 Transfer NB: The below transactions which were previously disclosed have been cancelled Deal Date Purchase/Sale Number of Securities Price per unit (GBP) 10/10/2008 Sale 602,293 24.7011 10/10/2008 Purchase 110,672 24.6092 (b) Derivatives transactions (other than options) Product name, Long/Short Number of Price per (e.g. CFD) (Note 6) Securities unit (GBP) CFD Long 200 24.28 CFD Long 320451 24.6892 CFD Long 4200 26.3912 CFD Long 19948 26.431 CFD Long 163182 26.4462 CFD Long 36113 26.4941 CFD Long 16907 26.6828 CFD Long 28341 26.7467 CFD Long 155151 26.9256 CFD Long 77800 27.6211 CFD Long 1500 27.9953 CFD Short 64248 24.5967 CFD Short 4070 25.5042 CFD Short 1500 26.3252 CFD Short 61 26.6744 CFD Short 8200 26.7119 CFD Short 33885 26.7352 CFD Short 31412 26.7662 CFD Short 7739 27.632 CFD Short 29800 27.722 NB: The below transactions which were previously disclosed have been cancelled Deal Date Long/Short Number of Securities Price per unit (GBP) 10/10/2008 Short 110,672 24.6092 10/10/2008 Long 602,293 24.7011 (c) Options transactions in respect of existing securities (i) Writing, selling, purchasing or varying Product name, Writing, Number of Exercise Type, e.g. Expiry Option money e.g. call selling, securities to price American, date paid/received option purchasing, which the option European etc. per unit (GBP) varying etc. relates (GBP) Put Selling 115000 52 EURO 19/12/2008 0 (ii) Exercising Product name, e.g. Number of Exercise price per call option securities unit (Note 5) (d) Other dealings (including new securities) (Note 4) Nature of transaction Details Price per unit (Note 8) (if applicable) (Note 5) 4. OTHER INFORMATION None Agreements, arrangements or understandings relating to options or derivatives Full details of any agreement, arrangement or understanding between the person disclosing and any other person relating to the voting rights of any relevant securities under any option referred to on this form or relating to the voting rights or future acquisition or disposal of any relevant securities to which any derivative referred to on this form is referenced. If none, this should be stated. Is a Supplemental Form 8 attached? (Note 9) YES Date of disclosure 14 October 2008 Contact name Geoff Smith Telephone number 020 7116 2913 If a connected EFM, name of offeree/offeror with which connected If a connected EFM, state nature of connection (Note 10) Notes The Notes on Form 8.3 can be viewed on the Takeover Panel's website at www.thetakeoverpanel.org.uk SUPPLEMENTAL FORM 8 DETAILS OF OPEN POSITIONS (This form should be attached to Form 8.1, Form 8.1(b)(ii) or Form 8.3, as appropriate) OPEN POSITIONS (Note 1) Product name, Written or Number of securities Exercise price Type, e.g. Expiry date e.g. call option purchased to which the option (Note 2) American, or derivative relates European etc. Option Purchased -50,000 64.0000 AMER 21/11/2008 Option Purchased -100,000 64.0000 AMER 21/11/2008 Option Purchased -125,000 45.0000 AMER 20/03/2009 Option Purchased 100,000 56.0000 AMER 18/12/2009 Option Purchased -115 5,200.0000 EURO 19/12/2008 Option Purchased -145 5,200.0000 EURO 19/12/2008 Option Purchased -270 6,400.0000 EURO 19/12/2008 Option Purchased -300 4,400.0000 EURO 19/12/2008 Option Purchased -300 4,400.0000 EURO 19/12/2008 Option Purchased -350 5,000.0000 EURO 19/12/2008 Option Purchased -500 7,000.0000 EURO 19/12/2008 Option Purchased 500 5,000.0000 EURO 19/12/2008 Option Purchased 350 4,600.0000 EURO 19/12/2008 Option Purchased 350 4,600.0000 EURO 19/12/2008 Notes 1. Where there are open option positions or open derivative positions (except for CFDs), full details should be given. Full details of any existing agreements to purchase or to sell should also be given on this form. 2. For all prices and other monetary amounts, the currency must be stated. For details of the Code's dealing disclosure requirements, see Rule 8 and its Notes which can be viewed on the Takeover Panel's website at www.thetakeoverpanel.org.uk

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Barclays (BARC)
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