Rule 8.3 - RIO TINTO PLC

FORM 8.3 DEALINGS BY PERSONS WITH INTERESTS IN SECURITIES REPRESENTING 1% OR MORE (Rule 8.3 of the City Code on Takeovers and Mergers) 1. KEY INFORMATION Name of person dealing BARCLAYS PLC (Note 1) Company dealt in RIO TINTO Class of relevant security ORD GBP0.10 to which the dealings being disclosed relate (Note 2) Date of dealing 01 September 2008 2. INTERESTS, SHORT POSITIONS AND RIGHTS TO SUBSCRIBE (a) Interests and short positions (following dealing) in the class of relevant security dealt in (Note 3) Long Short Number (%) Number (%) (1) Relevant 46,640,744 4.67% 639,309 0.06% securities (2) Derivatives 622,658 0.06% 1,956,231 0.20% (other than options) (3) Options and 101,200 0.01% 101,400 0.01% agreements to purchase/sell Total 47,364,602 4.75% 2,696,940 0.27% (b) Interests and short positions in relevant securities of the company, other than the class dealt in (Note 3) Class of Long Short relevant security: Number (%) Number (%) (1) Relevant securities (2) Derivatives (other than options) (3) Options and agreements to purchase/sell Total (c) Rights to subscribe (Note 3) Class of relevant security: Details 3. DEALINGS (Note 4) (a) Purchases and sales Purchase/sale Number of Securities Price per unit (GBP) Purchase 1,057 50.1000 Purchase 4,028 50.1000 Purchase 1,500 52.5268 Purchase 3,564 50.1000 Purchase 30 63.1000 EUR Purchase 779 52.2900 Purchase 340 52.2900 Purchase 1,462 52.2900 Purchase 95 52.2900 Sale 40 51.0560 Sale 115 51.4560 Sale 11,000 50.1000 Sale 2,000 51.4602 Sale 20 53.3830 Sale 3,564 50.1000 Sale 51 51.0630 Sale 168 51.5730 Sale 20 51.7560 Sale 91 51.8405 Sale 23 51.7290 Sale 3,564 50.1000 Sale 70 50.2824 Sale 105 51.7100 Sale 65 51.6531 Sale 180 50.0500 Sale 629 51.0491 Sale 500 62.0300 EUR Sale 1,439 50.1000 Sale 4,028 50.2624 (b) Derivatives transactions (other than options) Product name, Long/Short Number of Price per (e.g. CFD) (Note 6) Securities unit (GBP) CFD Long 2228 50.1616 CFD Long 8000 50.5349 CFD Long 52388 50.6493 CFD Long 20315 51.1388 CFD Long 300 51.1633 CFD Long 1545 51.6752 CFD Short 14170 50.0575 CFD Short 42000 50.1172 CFD Short 300 51.1633 CFD Short 72292 51.1967 CFD Short 1322 51.3189 CFD Short 6500 51.3439 CFD Short 2837 51.5381 CFD Short 1000 51.6258 CFD Short 5826 51.6736 CFD Short 1800 51.803 CFD Short 9500 52.1681 CFD Short 1500 52.5268 CFD Short 9500 52.6245 (c) Options transactions in respect of existing securities (i) Writing, selling, purchasing or varying Product name, Writing, Number of Exercise Type, e.g. Expiry Option money e.g. call selling, securities to price American, date paid/received option purchasing, which the option European etc. per unit (GBP) varying etc. relates (GBP) (ii) Exercising Product name, e.g. Number of Exercise price per call option securities unit (Note 5) (d) Other dealings (including new securities) (Note 4) Nature of transaction Details Price per unit (Note 8) (if applicable) (Note 5) 4. OTHER INFORMATION None Agreements, arrangements or understandings relating to options or derivatives Full details of any agreement, arrangement or understanding between the person disclosing and any other person relating to the voting rights of any relevant securities under any option referred to on this form or relating to the voting rights or future acquisition or disposal of any relevant securities to which any derivative referred to on this form is referenced. If none, this should be stated. Is a Supplemental Form 8 attached? (Note 9) YES Date of disclosure 02 September 2008 Contact name Geoff Smith Telephone number 020 7116 2913 If a connected EFM, name of offeree/offeror with which connected If a connected EFM, state nature of connection (Note 10) Notes The Notes on Form 8.3 can be viewed on the Takeover Panel's website at www.thetakeoverpanel.org.uk SUPPLEMENTAL FORM 8 DETAILS OF OPEN POSITIONS (This form should be attached to Form 8.1, Form 8.1(b)(ii) or Form 8.3, as appropriate) OPEN POSITIONS (Note 1) Product name, Written or Number of securities Exercise price Type, e.g. Expiry date e.g. call option purchased to which the option (Note 2) American, or derivative relates European etc. Option Purchased 100,000 56.0000 AMER 18/12/2009 Option Purchased -100,000 64.0000 AMER 21/11/2008 Option Purchased 350 4,600.0000 EURO 19/12/2008 Option Purchased 350 4,600.0000 EURO 19/12/2008 Option Purchased 300 5,000.0000 EURO 19/12/2008 Option Purchased 200 5,000.0000 EURO 19/12/2008 Option Purchased -135 5,200.0000 EURO 19/12/2008 Option Purchased -145 5,200.0000 EURO 19/12/2008 Option Purchased -200 7,000.0000 EURO 19/12/2008 Option Purchased -270 6,400.0000 EURO 19/12/2008 Option Purchased -300 7,000.0000 EURO 19/12/2008 Option Purchased -350 5,000.0000 EURO 19/12/2008 Notes 1. Where there are open option positions or open derivative positions (except for CFDs), full details should be given. Full details of any existing agreements to purchase or to sell should also be given on this form. 2. For all prices and other monetary amounts, the currency must be stated. For details of the Code's dealing disclosure requirements, see Rule 8 and its Notes which can be viewed on the Takeover Panel's website at www.thetakeoverpanel.org.uk

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Barclays (BARC)
UK 100

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