Rule 8.3 - RIO TINTO PLC

FORM 8.3 DEALINGS BY PERSONS WITH INTERESTS IN SECURITIES REPRESENTING 1% OR MORE (Rule 8.3 of the City Code on Takeovers and Mergers) 1. KEY INFORMATION Name of person dealing BARCLAYS PLC (Note 1) Company dealt in RIO TINTO Class of relevant security ORD GBP0.10 to which the dealings being disclosed relate (Note 2) Date of dealing 31 January 2008 2. INTERESTS, SHORT POSITIONS AND RIGHTS TO SUBSCRIBE (a) Interests and short positions (following dealing) in the class of relevant security dealt in (Note 3) Long Short Number (%) Number (%) (1) Relevant 48,346,523 4.85% 1,078,384 0.11% securities (2) Derivatives 2,411,114 0.24% 86,363 0.01% (other than options) (3) Options and 2,800 0.00% 700,810 0.07% agreements to purchase/sell Total 50,760,437 5.09% 1,865,557 0.19% (b) Interests and short positions in relevant securities of the company, other than the class dealt in (Note 3) Class of Long Short relevant security: Number (%) Number (%) (1) Relevant securities (2) Derivatives (other than options) (3) Options and agreements to purchase/sell Total (c) Rights to subscribe (Note 3) Class of relevant security: Details 3. DEALINGS (Note 4) (a) Purchases and sales Purchase/sale Number of Securities Price per unit (GBP) Purchase 26,350 49.5600 Purchase 36,850 49.5600 Purchase 50 48.9976 Purchase 3,587 49.0488 Purchase 57 49.5600 Purchase 1,000 48.1241 Purchase 2,531 49.5600 Purchase 2,196 49.1658 Purchase 78 49.5600 Purchase 886 49.5600 Purchase 7,738 48.9108 Purchase 47 49.5600 Purchase 235 49.5600 Purchase 39 48.8100 Purchase 1,040 49.5600 Purchase 49 65.1200 EUR Purchase 250 Transfer Purchase 3,400 48.7167 Purchase 2,779 48.6573 Purchase 36,978 48.1900 Purchase 100 65.8000 EUR Purchase 7,738 48.9108 Purchase 13,668 49.5600 Purchase 3,690 49.5600 Purchase 3,514 49.0688 Purchase 101 48.9000 Purchase 3,941 49.5600 Purchase 7,838 49.5600 Purchase 52,691 48.7178 Purchase 7,915 48.6409 Purchase 1,459 49.5600 Purchase 100 65.1200 EUR Purchase 1,109 49.5600 Purchase 5,109 49.5600 Purchase 10,929 49.5600 Purchase 1,017 49.5600 Sale 14,834 49.5600 Sale 700 48.4798 Sale 800 48.4798 Sale 579 49.5600 Sale 16,585 48.6143 Sale 59,863 48.6351 Sale 42,268 49.4400 Sale 78 49.5600 Sale 13 48.1550 Sale 36,850 49.5600 Sale 2,779 48.6573 Sale 7,838 49.5600 Sale 919 Transfer Sale 2,769 Transfer Sale 7,738 48.9108 Sale 35 48.1500 Sale 3,762 49.5600 Sale 6,810 49.5600 Sale 1,347 49.5600 Sale 70 48.7500 Sale 78 48.8376 Sale 26,350 49.5600 Sale 20,000 49.5600 Sale 100 48.0032 Sale 677 48.7057 Sale 50 48.5400 Sale 2,779 48.6573 Sale 2,253 49.5600 Sale 9,250 48.6046 Sale 15,291 48.6691 Sale 18,242 48.5275 (b) Derivatives transactions (other than options) Product name, Long/Short Number of Price per (e.g. CFD) (Note 6) Securities unit (GBP) CFD Short 1000 48.1241 CFD Short 786 48.4861 CFD Short 7129 48.6579 CFD Short 3400 48.7167 CFD Short 52691 48.7178 CFD Short 7738 48.9107 CFD Short 3514 49.0688 CFD Long 8435 48.5079 CFD Long 18242 48.5274 CFD Long 9250 48.6045 CFD Long 59863 48.6351 CFD Long 2779 48.6573 CFD Long 15291 48.669 CFD Long 46 48.6766 CFD Long 1043 48.6974 CFD Long 8150 48.7243 CFD Long 811 48.7467 (c) Options transactions in respect of existing securities (i) Writing, selling, purchasing or varying Product name, Writing, Number of Exercise Type, e.g. Expiry Option money e.g. call selling, securities to price American, date paid/received option purchasing, which the option European etc. per unit (GBP) varying etc. relates (GBP) (ii) Exercising Product name, e.g. Number of Exercise price per call option securities unit (Note 5) (d) Other dealings (including new securities) (Note 4) Nature of transaction Details Price per unit (Note 8) (if applicable) (Note 5) 4. OTHER INFORMATION None Agreements, arrangements or understandings relating to options or derivatives Full details of any agreement, arrangement or understanding between the person disclosing and any other person relating to the voting rights of any relevant securities under any option referred to on this form or relating to the voting rights or future acquisition or disposal of any relevant securities to which any derivative referred to on this form is referenced. If none, this should be stated. Is a Supplemental Form 8 attached? (Note 9) YES Date of disclosure 01 February 2008 Contact name Geoff Smith Telephone number 020 7116 2913 If a connected EFM, name of offeree/offeror with which connected If a connected EFM, state nature of connection (Note 10) Notes The Notes on Form 8.3 can be viewed on the Takeover Panel's website at www.thetakeoverpanel.org.uk SUPPLEMENTAL FORM 8 DETAILS OF OPEN POSITIONS (This form should be attached to Form 8.1, Form 8.1(b)(ii) or Form 8.3, as appropriate) OPEN POSITIONS (Note 1) Product name, Written or Number of securities Exercise price Type, e.g. Expiry date e.g. call option purchased to which the option (Note 2) American, or derivative relates European etc. Option Purchased 150 4,400.0000 EURO 20/03/2008 Option Purchased -300,000 52.0000 AMER 15/02/2008 Option Purchased -100,000 30.0000 AMER 20/06/2008 Option Purchased -300 3,800.0000 EURO 20/06/2008 Option Purchased -250 2,500.0000 EURO 20/06/2008 Option Purchased -250 5,200.0000 EURO 20/03/2008 Option Purchased -10 5,200.0000 EURO 19/12/2008 Option Purchased 50 5,400.0000 EURO 20/03/2008 Option Purchased -300,000 56.0000 AMER 15/02/2008 Option Purchased 125 4,400.0000 EURO 20/06/2008 Option Purchased 500 5,600.0000 EURO 15/02/2008 Option Purchased 150 4,000.0000 EURO 20/03/2008 Option Purchased 250 6,000.0000 EURO 15/02/2008 Option Purchased 250 6,000.0000 EURO 15/02/2008 Option Purchased 250 3,800.0000 EURO 20/06/2008 Option Purchased 250 3,000.0000 EURO 20/06/2008 Option Purchased 350 4,600.0000 EURO 19/12/2008 Option Purchased 350 4,600.0000 EURO 19/12/2008 Option Purchased 125 4,400.0000 EURO 20/06/2008 Notes 1. Where there are open option positions or open derivative positions (except for CFDs), full details should be given. Full details of any existing agreements to purchase or to sell should also be given on this form. 2. For all prices and other monetary amounts, the currency must be stated. For details of the Code's dealing disclosure requirements, see Rule 8 and its Notes which can be viewed on the Takeover Panel's website at www.thetakeoverpanel.org.uk

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Barclays (BARC)
UK 100

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