Rule 8.3 - RIO TINTO PLC

FORM 8.3 DEALINGS BY PERSONS WITH INTERESTS IN SECURITIES REPRESENTING 1% OR MORE (Rule 8.3 of the City Code on Takeovers and Mergers) 1. KEY INFORMATION Name of person dealing BARCLAYS PLC (Note 1) Company dealt in RIO TINTO Class of relevant security ORD GBP0.10 to which the dealings being disclosed relate (Note 2) Date of dealing 23 June 2008 2. INTERESTS, SHORT POSITIONS AND RIGHTS TO SUBSCRIBE (a) Interests and short positions (following dealing) in the class of relevant security dealt in (Note 3) Long Short Number (%) Number (%) (1) Relevant 44,701,469 4.48% 1,089,463 0.11% securities (2) Derivatives 862,945 0.09% 2,222,490 0.22% (other than options) (3) Options and 101,200 0.01% 1,030 0.00% agreements to purchase/sell Total 45,665,614 4.58% 3,312,983 0.33% (b) Interests and short positions in relevant securities of the company, other than the class dealt in (Note 3) Class of Long Short relevant security: Number (%) Number (%) (1) Relevant securities (2) Derivatives (other than options) (3) Options and agreements to purchase/sell Total (c) Rights to subscribe (Note 3) Class of relevant security: Details 3. DEALINGS (Note 4) (a) Purchases and sales Purchase/sale Number of Securities Price per unit (GBP) Purchase 84 59.3900 Purchase 134 60.4208 Purchase 21,752 59.9909 Purchase 19 Transfer Purchase 195 59.7400 Purchase 2,400 59.7157 Purchase 100 59.5500 Purchase 7,88 59.6546 Purchase 23,744 59.7400 Purchase 844 59.2300 Purchase 84 59.7400 Purchase 47 59.4270 Purchase 214 59.7400 Purchase 12,248 59.7400 Purchase 4,367 59.5229 Purchase 722 60.4500 Purchase 659 60.4500 Purchase 26,410 59.7400 Purchase 244 60.0500 Purchase 44,270 59.8000 Purchase 9,681 59.8000 Purchase 412 Transfer Purchase 4,066 60.0672 Sale 134 60.4208 Sale 49,378 59.4626 Sale 19 Transfer Sale 14,500 59.7400 Sale 1,374 59.5339 Sale 26,100 60.0532 Sale 200 59.3500 Sale 3 59.3965 Sale 1,200 58.9978 Sale 721 59.5300 Sale 50 59.6876 Sale 1,447 59.8000 Sale 130 59.2100 Sale 35 59.5460 Sale 55 59.6445 Sale 57 59.7400 Sale 11,777 59.7400 Sale 100 59.6875 Sale 2,000 59.4090 Sale 5,670 59.7400 Sale 46 59.4135 Sale 100 59.6875 Sale 100 59.5460 Sale 1,148 61.2816 Sale 125 59.6010 Sale 100 59.7700 Sale 117 59.6500 Sale 3,541 59.5062 Sale 27 59.7400 (b) Derivatives transactions (other than options) Product name, Long/Short Number of Price per (e.g. CFD) (Note 6) Securities unit (GBP) CFD Long 1200 58.9978 CFD Long 200 59.35 CFD Long 2000 59.409 CFD Long 49378 59.4625 CFD Long 3541 59.5061 CFD Long 1227 59.521 CFD Long 1374 59.5339 CFD Long 125 59.601 CFD Long 3038 59.752 CFD Long 26100 60.0531 CFD Long 1148 61.2816 CFD Short 4367 59.5229 CFD Short 7887 59.6545 CFD Short 2400 59.7157 CFD Short 21752 59.9909 CFD Short 4066 60.0672 (c) Options transactions in respect of existing securities (i) Writing, selling, purchasing or varying Product name, Writing, Number of Exercise Type, e.g. Expiry Option money e.g. call selling, securities to price American, date paid/received option purchasing, which the option European etc. per unit (GBP) varying etc. relates (GBP) (ii) Exercising Product name, e.g. Number of Exercise price per call option securities unit (Note 5) (d) Other dealings (including new securities) (Note 4) Nature of transaction Details Price per unit (Note 8) (if applicable) (Note 5) 4. OTHER INFORMATION None Agreements, arrangements or understandings relating to options or derivatives Full details of any agreement, arrangement or understanding between the person disclosing and any other person relating to the voting rights of any relevant securities under any option referred to on this form or relating to the voting rights or future acquisition or disposal of any relevant securities to which any derivative referred to on this form is referenced. If none, this should be stated. Is a Supplemental Form 8 attached? (Note 9) YES Date of disclosure 24 June 2008 Contact name Geoff Smith Telephone number 020 7116 2913 If a connected EFM, name of offeree/offeror with which connected If a connected EFM, state nature of connection (Note 10) Notes The Notes on Form 8.3 can be viewed on the Takeover Panel's website at www.thetakeoverpanel.org.uk SUPPLEMENTAL FORM 8 DETAILS OF OPEN POSITIONS (This form should be attached to Form 8.1, Form 8.1(b)(ii) or Form 8.3, as appropriate) OPEN POSITIONS (Note 1) Product name, Written or Number of securities Exercise price Type, e.g. Expiry date e.g. call option purchased to which the option (Note 2) American, or derivative relates European etc. Option Purchased 100,000 56.0000 AMER 18/12/2009 Option Purchased 500 5,000.0000 EURO 19/12/2008 Option Purchased 350 4,600.0000 EURO 19/12/2008 Option Purchased 350 4,600.0000 EURO 19/12/2008 Option Purchased -135 5,200.0000 EURO 19/12/2008 Option Purchased -145 5,200.0000 EURO 19/12/2008 Option Purchased -250 5,200.0000 EURO 19/09/2008 Option Purchased -500 7,000.0000 EURO 19/12/2008 Notes 1. Where there are open option positions or open derivative positions (except for CFDs), full details should be given. Full details of any existing agreements to purchase or to sell should also be given on this form. 2. For all prices and other monetary amounts, the currency must be stated. For details of the Code's dealing disclosure requirements, see Rule 8 and its Notes which can be viewed on the Takeover Panel's website at www.thetakeoverpanel.org.uk

Companies

Barclays (BARC)
UK 100

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