Rule 8.3 - RIO TINTO PLC

FORM 8.3 DEALINGS BY PERSONS WITH INTERESTS IN SECURITIES REPRESENTING 1% OR MORE (Rule 8.3 of the City Code on Takeovers and Mergers) 1. KEY INFORMATION Name of person dealing BARCLAYS PLC (Note 1) Company dealt in RIO TINTO Class of relevant security ORD GBP0.10 to which the dealings being disclosed relate (Note 2) Date of dealing 08 September 2008 2. INTERESTS, SHORT POSITIONS AND RIGHTS TO SUBSCRIBE (a) Interests and short positions (following dealing) in the class of relevant security dealt in (Note 3) Long Short Number (%) Number (%) (1) Relevant 46,430,362 4.65% 747,776 0.07% securities (2) Derivatives 593,606 0.06% 1,991,352 0.20% (other than options) (3) Options and 101,200 0.01% 101,400 0.01% agreements to purchase/sell Total 47,125,168 4.72% 2,840,528 0.28% (b) Interests and short positions in relevant securities of the company, other than the class dealt in (Note 3) Class of Long Short relevant security: Number (%) Number (%) (1) Relevant securities (2) Derivatives (other than options) (3) Options and agreements to purchase/sell Total (c) Rights to subscribe (Note 3) Class of relevant security: Details 3. DEALINGS (Note 4) (a) Purchases and sales Purchase/sale Number of Securities Price per unit (GBP) Purchase 45 55.9100 EUR Purchase 1,417 45.2305 Purchase 219 45.3468 Purchase 6,700 45.6519 Purchase 40 55.0000 EUR Purchase 1,485 43.7978 Purchase 619 Transfer Purchase 8,400 45.0989 Purchase 13 43.7610 Purchase 1,485 43.7967 Purchase 6,960 44.7324 Sale 36 44.9532 Sale 65,000 47.9775 Sale 2,467 Transfer Sale 1,485 43.7978 Sale 24 43.3308 Sale 974 44.7985 Sale 17,000 44.9000 Sale 13 57.8800 EUR Sale 401 44.8533 Sale 15,011 44.9122 Sale 43,926 44.8141 Sale 175 45.5500 Sale 600 45.5350 (b) Derivatives transactions (other than options) Product name, Long/Short Number of Price per (e.g. CFD) (Note 6) Securities unit (GBP) CFD Long 974 44.7985 CFD Long 43926 44.8141 CFD Long 401 44.8532 CFD Long 15011 44.9122 CFD Long 600 45.535 CFD Short 1485 43.7978 CFD Short 6960 44.7324 CFD Short 8400 45.0989 CFD Short 219 45.3468 CFD Short 6700 45.6519 (c) Options transactions in respect of existing securities (i) Writing, selling, purchasing or varying Product name, Writing, Number of Exercise Type, e.g. Expiry Option money e.g. call selling, securities to price American, date paid/received option purchasing, which the option European etc. per unit (GBP) varying etc. relates (GBP) (ii) Exercising Product name, e.g. Number of Exercise price per call option securities unit (Note 5) (d) Other dealings (including new securities) (Note 4) Nature of transaction Details Price per unit (Note 8) (if applicable) (Note 5) 4. OTHER INFORMATION None Agreements, arrangements or understandings relating to options or derivatives Full details of any agreement, arrangement or understanding between the person disclosing and any other person relating to the voting rights of any relevant securities under any option referred to on this form or relating to the voting rights or future acquisition or disposal of any relevant securities to which any derivative referred to on this form is referenced. If none, this should be stated. Is a Supplemental Form 8 attached? (Note 9) YES Date of disclosure 09 September 2008 Contact name Geoff Smith Telephone number 020 7116 2913 If a connected EFM, name of offeree/offeror with which connected If a connected EFM, state nature of connection (Note 10) Notes The Notes on Form 8.3 can be viewed on the Takeover Panel's website at www.thetakeoverpanel.org.uk SUPPLEMENTAL FORM 8 DETAILS OF OPEN POSITIONS (This form should be attached to Form 8.1, Form 8.1(b)(ii) or Form 8.3, as appropriate) OPEN POSITIONS (Note 1) Product name, Written or Number of securities Exercise price Type, e.g. Expiry date e.g. call option purchased to which the option (Note 2) American, or derivative relates European etc. Option Purchased 100,000 56.0000 AMER 18/12/2009 Option Purchased -100,000 64.0000 AMER 21/11/2008 Option Purchased 350 5,000.0000 EURO 19/12/2008 Option Purchased 350 4,600.0000 EURO 19/12/2008 Option Purchased 350 4,600.0000 EURO 19/12/2008 Option Purchased 150 5,000.0000 EURO 19/12/2008 Option Purchased -135 5,200.0000 EURO 19/12/2008 Option Purchased -145 5,200.0000 EURO 19/12/2008 Option Purchased -150 7,000.0000 EURO 19/12/2008 Option Purchased -270 6,400.0000 EURO 19/12/2008 Option Purchased -350 7,000.0000 EURO 19/12/2008 Option Purchased -350 5,000.0000 EURO 19/12/2008 Notes 1. Where there are open option positions or open derivative positions (except for CFDs), full details should be given. Full details of any existing agreements to purchase or to sell should also be given on this form. 2. For all prices and other monetary amounts, the currency must be stated. For details of the Code's dealing disclosure requirements, see Rule 8 and its Notes which can be viewed on the Takeover Panel's website at www.thetakeoverpanel.org.uk

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Barclays (BARC)
UK 100

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