Rule 8.3 - RIO TINTO PLC

FORM 8.3 DEALINGS BY PERSONS WITH INTERESTS IN SECURITIES REPRESENTING 1% OR MORE (Rule 8.3 of the City Code on Takeovers and Mergers) 1. KEY INFORMATION Name of person dealing BARCLAYS PLC (Note 1) Company dealt in RIO TINTO Class of relevant security ORD GBP0.10 to which the dealings being disclosed relate (Note 2) Date of dealing 11 September 2008 2. INTERESTS, SHORT POSITIONS AND RIGHTS TO SUBSCRIBE (a) Interests and short positions (following dealing) in the class of relevant security dealt in (Note 3) Long Short Number (%) Number (%) (1) Relevant 46,614,513 4.67% 712,498 0.07% securities (2) Derivatives 590,249 0.06% 1,955,196 0.20% (other than options) (3) Options and 101,200 0.01% 101,400 0.01% agreements to purchase/sell Total 47,305,962 4.74% 2,819,094 0.28% (b) Interests and short positions in relevant securities of the company, other than the class dealt in (Note 3) Class of Long Short relevant security: Number (%) Number (%) (1) Relevant securities (2) Derivatives (other than options) (3) Options and agreements to purchase/sell Total (c) Rights to subscribe (Note 3) Class of relevant security: Details 3. DEALINGS (Note 4) (a) Purchases and sales Purchase/sale Number of Securities Price per unit (GBP) Purchase 35,958 41.4427 Purchase 6,071 41.6277 Purchase 3,000 42.0280 Purchase 16,500 42.6500 Purchase 4,794 41.8961 Purchase 47 Transfer Purchase 7,500 40.9200 Purchase 45,074 41.5741 Purchase 1,981 42.5264 Purchase 8,429 42.1754 Purchase 8,600 40.9200 Purchase 2,500 40.9968 Purchase 2,500 41.9500 Purchase 22,187 41.5646 Purchase 49,690 41.6734 Purchase 10,000 41.3992 Purchase 20,500 44.1713 Purchase 117,154 41.1148 Purchase 2,400 42.0280 Purchase 272 42.4516 Purchase 13 52.0100 EUR Purchase 120 41.8468 Purchase 2,271 42.0000 Purchase 588 41.6531 Purchase 435 41.5800 Purchase 250 40.3800 Purchase 644 42.4516 Purchase 878 42.4855 Purchase 161 41.6900 Sale 25 42.2930 Sale 2,339 41.5350 Sale 10,000 41.8817 Sale 9,257 41.5800 Sale 241 41.2540 Sale 7,500 42.1416 Sale 88 42.4948 Sale 4,500 40.5617 Sale 50 52.0700 EUR Sale 45,451 41.2229 Sale 2,200 40.7342 Sale 5,056 41.3379 Sale 11,500 42.5526 Sale 18,103 41.7672 Sale 13,586 41.2155 Sale 155 40.8840 Sale 1,600 40.5613 Sale 54 42.2700 Sale 30,400 41.6500 Sale 3,344 41.5800 Sale 5,352 41.5800 Sale 33 42.5336 Sale 600 41.9300 Sale 47 Transfer Sale 217 Transfer Sale 100 41.6628 (b) Derivatives transactions (other than options) Product name, Long/Short Number of Price per (e.g. CFD) (Note 6) Securities unit (GBP) CFD Long 1600 40.5613 CFD Long 4500 40.5616 CFD Long 2200 40.7342 CFD Long 13586 41.2154 CFD Long 45451 41.2229 CFD Long 5056 41.3378 CFD Long 17189 41.4533 CFD Long 3276 41.5884 CFD Long 30400 41.65 CFD Long 32386 41.6656 CFD Long 18103 41.7671 CFD Long 10000 41.8817 CFD Long 8087 42.0273 CFD Long 11500 42.5526 CFD Short 16100 40.92 CFD Short 2500 40.9968 CFD Short 117154 41.1147 CFD Short 10000 41.3992 CFD Short 35958 41.4426 CFD Short 22187 41.5645 CFD Short 45074 41.574 CFD Short 6071 41.6277 CFD Short 49690 41.6734 CFD Short 8429 42.1753 CFD Short 878 42.4855 CFD Short 1981 42.5263 (c) Options transactions in respect of existing securities (i) Writing, selling, purchasing or varying Product name, Writing, Number of Exercise Type, e.g. Expiry Option money e.g. call selling, securities to price American, date paid/received option purchasing, which the option European etc. per unit (GBP) varying etc. relates (GBP) Call Purchase 50,000 64 AMER 21/11/2008 0.178 (ii) Exercising Product name, e.g. Number of Exercise price per call option securities unit (Note 5) (d) Other dealings (including new securities) (Note 4) Nature of transaction Details Price per unit (Note 8) (if applicable) (Note 5) 4. OTHER INFORMATION None Agreements, arrangements or understandings relating to options or derivatives Full details of any agreement, arrangement or understanding between the person disclosing and any other person relating to the voting rights of any relevant securities under any option referred to on this form or relating to the voting rights or future acquisition or disposal of any relevant securities to which any derivative referred to on this form is referenced. If none, this should be stated. Is a Supplemental Form 8 attached? (Note 9) YES Date of disclosure 12 September 2008 Contact name Geoff Smith Telephone number 020 7116 2913 If a connected EFM, name of offeree/offeror with which connected If a connected EFM, state nature of connection (Note 10) Notes The Notes on Form 8.3 can be viewed on the Takeover Panel's website at www.thetakeoverpanel.org.uk SUPPLEMENTAL FORM 8 DETAILS OF OPEN POSITIONS (This form should be attached to Form 8.1, Form 8.1(b)(ii) or Form 8.3, as appropriate) OPEN POSITIONS (Note 1) Product name, Written or Number of securities Exercise price Type, e.g. Expiry date e.g. call option purchased to which the option (Note 2) American, or derivative relates European etc. Option Purchased -50,000 64.0000 AMER 21/11/2008 Option Purchased -100,000 64.0000 AMER 21/11/2008 Option Purchased 100,000 56.0000 AMER 18/12/2009 Option Purchased -135 5,200.0000 EURO 19/12/2008 Option Purchased -145 5,200.0000 EURO 19/12/2008 Option Purchased -150 7,000.0000 EURO 19/12/2008 Option Purchased -270 6,400.0000 EURO 19/12/2008 Option Purchased -350 7,000.0000 EURO 19/12/2008 Option Purchased -350 5,000.0000 EURO 19/12/2008 Option Purchased 350 5,000.0000 EURO 19/12/2008 Option Purchased 350 4,600.0000 EURO 19/12/2008 Option Purchased 350 4,600.0000 EURO 19/12/2008 Option Purchased 150 5,000.0000 EURO 19/12/2008 Notes 1. Where there are open option positions or open derivative positions (except for CFDs), full details should be given. Full details of any existing agreements to purchase or to sell should also be given on this form. 2. For all prices and other monetary amounts, the currency must be stated. For details of the Code's dealing disclosure requirements, see Rule 8 and its Notes which can be viewed on the Takeover Panel's website at www.thetakeoverpanel.org.uk

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Barclays (BARC)
UK 100

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