Assays boosts confidence - exceptional 38.9% MREO

RNS Number : 9326P
Castillo Copper Limited
15 February 2023
 

A picture containing text, clipart Description automatically generated


15 February 2023

 

 

CASTILLO COPPER LIMITED
("Castillo", or the "Company")

 

 

Diamond core TREO assay boosts confidence; exceptional 38.9% MREO

 

Castillo Copper Limited (LSE and ASX: CCZ), a base metal explorer primarily focused on copper across Australia and Zambia, is delighted with the latest assays results for the Tors Tank and Fence Gossan Prospects, as collectively they materially increase confidence in the shallow, clay-hosted, Rare Earth Element ("REE") discovery across the central part of the BHA Project's East Zone (Appendix A).

 

HIGHLIGHTS:

 

· The assay results for diamond core from TT_005DD - undertaken at the Tors Tank Prospect (refer Appendix A) - significantly boosts confidence in the shallow, clay-hosted, rare-earth element discovery1, with the best intercept:

13m @ 1,550ppm Total Rare Earth Oxides ("TREO") from 5m 

Notably, high value Magnetic REO (Nd+Pr+Dy+Tb) represented an exceptional 38.9% of the TREO grade vs 25% peer average2

· Re-assays of 4m composite samples at Tors Tank and Fence Gossan to 1m provided greater clarity on the underlying geology, whilst delivering further evidence of an extensive, shallow REE mineralisation system - the best intercepts comprise:

17m @ 1,605ppm TREO from 2m and 1m @ 3,236 TREO from 19m (FG_003RC)

10m @ 1,013ppm TREO from 49m (FG_001RC)

6m @ 1,480ppm TREO from 7m (FG_004RC)

5m @ 1,598ppm TREO from 14m (TT_002RC)

4m @ 1,342ppm TREO from 28m (FG_004RC)

2m @ 3,491ppm TREO from 7m (TT_003RC)

· Assays for circa 70% of the recent hand auger surface sampling campaign across Fence Gossan delineated a sizeable 4.5km2 anomalous area for REE mineralisation:

A preliminary interpretation suggests there are several more prime targets to test-drill that could potentially extend known mineralisation between the Fence Gossan and Tors Tank Prospects 

· A fuller interpretation will be released once all the assay results for the auger sampling campaign and drill-holes RT_002-004RC are received from the laboratory

Dr Dennis Jensen, Managing Director of Castillo Copper, said: "The Board is delighted with the latest results, especially the diamond core assay at Tors Tank and exceptional MREO value, as it increases confidence in the underlying REE system. In addition, the hand auger surface sampling campaign is proving to be a treasure trove of insights, with several new targets now on the radar. The Board looks forward to receiving the remaining assays and charting the next phase of the exploration campaign."

 

ASSAYS BOOST REE CONFIDENCE AT BROKEN HILL

Diamond core

Drill-hole TT_005DD, which produced diamond core from the Tors Tank Prospect (refer Figure 1), returned an excellent assay result, with the best intercept: 13m @ 1,550ppm TREO from 5m.

More significantly, the high value Magnetic REO, which comprises in-demand REEs (Nd+Pr+Dy+Tb), represented an exceptional 38.9% of the TREO grade which is well above the 25% average among the peer group2.

 

FIGURE 1 : TORS TANK DIAMOND CORE FROM 5.3-11.8M (TT_OO5DD)

A picture containing text Description automatically generated

A picture containing text Description automatically generated

Source: CCZ geology team

Re-assays: Tors Tank and Fence Gossan

To gain greater insights of the underlying geology at Tors Tank and Fence Gossan, the 4m composite samples were re-assayed to 1m - with the best results highlighted in Figure 2, with up to 3,491ppm TREO recorded. Interpreting the re-assays provides clearer evidence that there is an extensive, shallow REE mineralisation system across the centre of the BHA Project's East Zone (refer Appendix A).

FIGURE 2: BEST "RC" INTERCEPTS TORS TANK / FENCE GOSSAN

Hole

From (m)

To (m)

Width (m)

TREO (ppm)

MREO (%)

TT_001RC

25

27

2

1,048

27.1%

TT_002RC

14

19

5

1,598

29.1%

TT_003RC

4

11

7

890

34.6%

 

12

13

1

1,103

28.4%

 

15

17

2

3,491

24.6%

FG_001RC

8

20

12

907

31.0%

 

49

59

10

1,013

24.7%

FG_002RC

11

16

5

1,065

28.9%

FG_003RC

2

19

17

1,605

28.6%

 

19

20

1

3,236

28.9%

FG_004RC

7

13

6

1,480

28.9%

 

28

32

4

1,342

22.9%

Source: CCZ geology team

Surface sampling: Fence Gossan

Around 70% of the hand auger surface sampling assays for the Fence Gossan Prospect have been returned. Pleasingly, the assays delineate a sizeable (circa 4.5km2) anomalous REE zone - refer to Figure 3 below.

Surface readings indicate anomalous areas to the south, south-west and north-west of the four recent cobalt-focussed Fence Gossan drill-holes which suggest possible higher mineralisation in these zones than identified in the drill-holes (Figure 3) .

Having reconciled these findings and performed a statistical analysis, the geology team believe surface sample readings with Ce > 100ppm is a likely indicator of higher grade REE mineralisation at depth. As such, these are interpreted to be prime targets for test-drilling that could extend known mineralisation between the Tors Tank and Fence Gossan Prospects.

FIGURE 3:  SURFACE MAPPED LITHOLOGY VS CERIUM CONTOURS (PPM)

Map Description automatically generated

Note: Coordinates in MGA94 - Z54; scale range cerium contours 20-230ppm.

Source: CCZ geology team / ALS Laboratory


For further information, please contact:   

 

Castillo Copper Limited

+61 8 6558 0886

Dr Dennis Jensen (Australia), Managing Director

Gerrard Hall (UK), Chairman

SI Capital Limited (Financial Adviser and Corporate Broker)

+44 (0)1483 413500

Nick Emerson


Gracechurch Group (Financial PR) 

+44 (0)20 4582 3500

Harry Chathli, Alexis Gore, Henry Gamble 

 

 

About Castillo Copper   

 

Castillo Copper Limited is an Australian-based explorer primarily focused on copper across Australia and Zambia. The group is embarking on a strategic transformation to morph into a mid-tier copper group underpinned by its core projects: 

· A large footprint in the Mt Isa copper-belt district, north-west Queensland, which delivers significant exploration upside through having several high-grade targets and a sizeable untested anomaly within its boundaries in a copper-rich region. 

· Four high-quality prospective assets across Zambia's copper-belt which is the second largest copper producer in Africa. 

· A large tenure footprint proximal to Broken Hill's world-class deposit that is prospective for zinc-silver-lead-copper-gold and platinoids.  

· Cangai Copper Mine in northern New South Wales, which is one of Australia's highest grading historic copper mines. 

 

The group is listed on the LSE and ASX under the ticker "CCZ." 

 

Competent Person's Statement

The information in this report that relates to Exploration Results and Mineral Resource Estimates for "BHA Project, East Zone" is based on information compiled or reviewed by Mr Mark Biggs.  Mr Biggs is a director of ROM Resources, a company which is a shareholder of Castillo Copper Limited.  ROM Resources provides ad hoc geological consultancy services to Castillo Copper Limited.  Mr Biggs is a member of the Australian Institute of Mining and Metallurgy (member #107188) and has sufficient experience of relevance to the styles of mineralisation and types of deposits under consideration, and to the activities undertaken, to qualify as a Competent Person as defined in the 2012 Edition of the Joint Ore Reserves Committee (JORC) Australasian Code for Reporting of Exploration Results, and Mineral Resources. Mr Biggs holds an AusIMM Online Course Certificate in 2012 JORC Code Reporting.  Mr Biggs also consents to the inclusion in this report of the matters based on information in the form and context in which it appears.

 

References

1)  CCZ ASX Release - 23 November 2022

2)  Nelson, S. "Rare earths rush showed no signs of abating in Q4 2022" 6 February 2023. Available at: https://www.proactiveinvestors.com.au/companies/news/1005217/rare-earths-rush-showed-no-signs-of-abating-in-q4-2022-1005217.html

 

 

 

 

APPENDIX A: BHA PROJECT'S EAST ZONE

FIGURE A1: BHA PROJECT's EAST ZONE - REE EXPLORATION FOOTPRINT

Diagram, schematic Description automatically generated

Source: CCZ geology team

FIGURE A2: BHA PROJECT

 

Diagram Description automatically generated

Source: CCZ geology team


APPENDIX B: REE RESULTS / TREO CONVERSION FACTOR

FIGURE B1: TORS TANK / FENCE GOSSAN - 1M INTERSECTIONS >500PPM TREO

Hole

From  (m)

To  (m)

Apparent

Width (m)

Ag

(g/t)

Th  (ppm)

U  (ppm)

TREO  (ppm)1

TREO-Ce  (ppm)

LREO  (ppm)

HREO  (ppm)

CREO

(%)

MREO

(%)

FG_001RC

3

4

1

0.05

20.2

7.1

864

511.78

751.75

112.58

26.5%

30.1%

 

8

20

12

0.07

7.7

13.0

907

539.26

788.62

118.24

26.3%

31.0%

 

49

59

10

0.03

11.1

17.0

1,013

595.88

860.49

152.98

24.9%

24.7%

FG_002RC

3

5

2

0.11

8.2

10.7

637

363.49

554.22

83.20

24.5%

26.3%

 

6

10

4

0.07

15.6

7.1

711

411.55

622.39

88.89

24.2%

27.2%

 

11

16

5

0.02

8.8

17.6

1,065

643.95

910.78

154.51

26.7%

28.9%

FG_003RC

2

19

17

0.08

14.3

19.6

1,605

1011.78

1378.22

226.81

26.7%

28.6%

 

19

20

1

0.11

1.8

47.6

3,236

2441.30

2079.08

1156.99

40.3%

28.9%

 

59

60

1

0.04

8.7

25.1

808

546.46

632.71

175.40

31.3%

26.0%

FG_004RC

7

13

6

0.21

18.4

10.4

1,480

863.25

1299.89

179.81

25.2%

28.9%

 

28

32

4

0.13

19.4

28.2

1,342

762.43

1185.14

156.78

21.9%

22.9%

 

48

57

9

0.08

9.7

24.1

848

477.63

736.43

111.69

23.2%

24.3%

 

61

63

2

0.07

17.3

7.8

782

432.64

689.41

92.71

22.0%

23.4%

TT_001RC

25

27

2

0.17

4.3

15.7

1,048

755.07

668.01

380.03

41.0%

27.1%

 

39

40

1

0.05

19.2

1.7

752

396.02

705.28

46.97

20.1%

25.8%

 

41

42

1

0.04

22.0

1.9

624

310.71

583.08

40.87

19.6%

24.7%

 

43

44

1

0.04

9.0

3.8

747

437.58

677.48

69.66

23.7%

29.0%

 

47

48

1

0.09

19.6

3.2

684

374.60

627.57

56.59

18.2%

20.3%

 

49

51

2

0.07

32.5

3.6

676

379.43

595.53

80.57

22.5%

23.6%

TT_002RC

14

19

5

0.72

0.9

7.4

1,598

959.58

1235.37

363.60

31.5%

29.1%

TT_003RC

4

11

7

0.23

1.2

8.6

890

586.78

708.95

181.16

32.8%

34.6%

 

12

13

1

0.08

1.8

14.0

1,103

676.16

805.70

297.95

34.6%

28.4%

 

15

17

1

0.14

1.8

15.0

3,491

3072.18

1281.72

2209.34

59.3%

24.6%

TT_005DD

5

18

13

0.38

3.0

12.4

1,550

1150.56

1123.35

427.05

40.1%

38.9%

 

67

68

1

0.12

6.8

8.2

722

443.76

599.73

122.88

30.5%

31.2%

TT_004RC

n/a

n/a











 













Notes:

1.  TT_001RC 39-52m composite also reports 6,388 ppm Ba (Barium); TT_003RC 1,140 ppm Ba.

2.  Two of the Lanthanum (La) assay from FG_003R returned >500ppm were re-analysed (514 and 527ppm, respectively).

3.  Verification has been undertaken by ROM Resources personnel.

4.  Sample results from ALS method ME-ICP81.

Source: ALS Adelaide  

TREO conversion factor

Conversion of elemental analysis (REE parts per million) to stoichiometric oxide (REO parts per million) was undertaken by ROM geological staff using the below (Figure B2) element to stoichiometric oxide conversion factors. 

FIGURE B2:  ELEMENT - CONVERSION FACTOR - OXIDE FORM

Rare Earth Element

Factor for Conversion

Rare Earth Oxide Common Form

Ce

1.2284

CeO2

Dy

1.1477

Dy2O3

Er

1.1435

Er2O3

Eu

1.1579

Eu2O3

Gd

1.1526

Gd2O3

Ho

1.1455

Ho2O3

La

1.1728

La2O3

Lu

1.1371

Lu2O3

Nd

1.1664

Nd2O3

Pr

1.2083

Pr6O11

Sm

1.1596

Sm2O3

Tb

1.1762

Tb4O7

Tm

1.1421

Tm2O3

Y

1.2699

Y2O3

Yb

1.1387

Yb2O3

Source: CCZ geology team

Rare earth oxide is the industry accepted form for reporting rare earths. The following calculations are used for compiling REO into their reporting and evaluation groups:

· TREO (Total Rare Earth Oxide) = La2O3 + CeO2 + Pr6O11 + Nd2O3 + Sm2O3 + Eu2O3 + Gd2O3 + Tb4O7 + Dy2O3 + Ho2O3 + Er2O3 + Tm2O3 + Yb2O3 + Y2O3 + Lu2O3.

· TREO-Ce = TREO - CeO2

· LREO (Light Rare Earth Oxide) = La2O3 + CeO2 + Pr6O11 + Nd2O3 + Sm2O3 

· HREO (Heavy Rare Earth Oxide) = Eu2O3 + Gd2O3 + Tb4O7 + Dy2O3 + Ho2O3 + Er2O3 + Tm2O3 + Yb2O3 + Y2O3 + Lu2O3

· CREO (Critical Rare Earth Oxide) = Nd2O3 + Eu2O3 + Tb4O7 + Dy2O3 + Y2O3

· MREO (Magnetic Rare Earth Oxide) = Pr6O11 + Nd2O3 + Sm2O3 + Gd2O3 + Tb4O7 + Dy2O3.

Total Rare Earth Oxides (TREO):

To calculate TREO an oxide conversion "factor" is applied to each rare-earth element assay. 

The "factor" equates an elemental assay to an oxide concentration for each element. Below is an example of the factor calculation for Lanthanum (La).

Relative Atomic Mass (La) = 138.9055

Relative Atomic Mass (O) = 15.9994

Oxide Formula = La2O3

Oxide Conversion Factor = 1/ ((2x 138.9055)/(2x 138.9055 + 3x 15.9994)) Oxide Conversion Factor = 1.173 (3 decimal places)

APPENDIX C: DRILLHOLE COORDINATES AFTER SURVEY

All drill-holes have now been surveyed, with coordinates showing only 0.5-4m errors in X and Y compared to the initial GPS readings (Figures C1-3). The total program consisted of 1,568m of RC and 137.7m of HQ diamond core.

FIGURE C1: TORS TANK SURVEYED DRILL COLLARS

HoleID

 Easting (GDA94)

Northing (GDA94)

AHD (m)

TDepth (m)

Grid Azimuth

Dip Horizontal

Hole Type

Start

End

TT_001RC

571356

6451399

191.2

120

193.1

-63.1

RC

30-Sep-22

1-Oct-22

TT_002RC

571473

6451248

191.4

108

188.6

-63.0

RC

1-Oct-22

2-Oct-22

TT_003RC

571421

6451278

193.1

140

192.1

-62.5

RC

2-Oct-22

3-Oct-22

TT_004RC

571230

6451498

189.9

120

186.8

-66.1

RC

3-Oct-22

4-Oct-22

TT_005DD

571427

6451276

193.0

137.7

187.2

-60.8

DDH

11-Oct-22

17-Oct-22

 




625.7






Source: CCZ geology team

FIGURE C2: FENCE GOSSAN SURVEYED DRILL COLLARS

HoleID

Easting (GDA94)

Northing (GDA94)

AHD (m)

Tdepth (m)

Grid Azimuth

DipH

Hole Type

Start

End

FG_001RC

576347

6453786

171.2

126

191.8

-64.9

RC

4-Oct-22

7-Oct-22

FG_002RC

576547

6453751

169.1

110

195.2

-65.2

RC

7-Oct-22

8-Oct-22

FG_003RC

576696

6453833

167.7

160

193.7

-67.9

RC

8-Oct-22

9-Oct-22

FG_004RC

575998

6453831

173.7

120

188.2

-64.2

RC

9-Oct-22

10-Oct-22

 




516






Source: CCZ geology team

 

FIGURE C3: REEFS TANK SURVEYED DRILL COLLARS

HoleID

Easting

Northing

AHD (m)

TD

Azimuth

DipH

Type

Start

Finish

RT_001RC

574106.703

6456242.501

179.7

120

188.0

-62.1

RC

10/10/2022

11/10/2022

RT_002RC

574120.601

6455468.441

188.1

204

189.2

-65.3

RC

9/11/2022

10/11/2022

RT_003RC

573418.409

6455244.784

191.7

120

186.4

-63.7

RC

10/11/2022

14/11/2022

RT_004RC

573726.282

6454924.984

186.6

120

190.2

-61.5

RC

14/11/2022

15/11/2022

 




564






Source: CCZ geology team

Figures C4 and C5 show a cross-section of the extent of downhole distribution of cobalt and cerium at Tors Tank.  Most of the major occurrences are at <50m depth.

FIGURE C4: TORS TANK - COBALT (PPM)

Timeline Description automatically generated with low confidence

Notes:

1.  View looking north-west.

2.  Vertical exaggeration 2:1

Source: CCZ geology team

FIGURE C5: TORS TANK CERIUM (PPM)

A picture containing chart Description automatically generated

Source: CCZ geology team

At Fence Gossan, a downhole cross-section shows the distribution of the rare earth element cerium (ppm), especially highlighting the anomalous zones near surface and a second zone at about 50m depth.  The high REE zones appear in extremely weathered clays derived from mostly pegmatite.

 

FIGURE C6:  FENCE GOSSAN CERIUM (PPM)

A picture containing text, indoor Description automatically generated

Source: CCZ geology team

 

 

 

APPENDIX D: JORC CODE, 2012 EDITION - TABLE 1

Section 1: Sampling Techniques and Data

Criteria

JORC Code explanation

Commentary

Sampling techniques

Nature and quality of sampling (e.g., cut channels, random chips, or specific specialised industry standard measurement tools appropriate to the minerals under investigation, such as down hole gamma sondes, or handheld XRF instruments, etc.). These examples should not be taken as limiting the broad meaning of sampling.

Include reference to measures taken to ensure sample representivity and the appropriate calibration of any measurement tools or systems used.

Aspects of the determination of mineralisation that are Material to the Public Report.

In cases where 'industry standard' work has been done this would be relatively simple (e.g., 'reverse circulation drilling was used to obtain 1 m samples from which 3 kg was pulverised to produce a 30g charge for fire assay'). In other cases, more explanation may be required, such as where there is coarse gold that has inherent sampling problems. Unusual commodities or mineralisation types (eg submarine nodules) may warrant disclosure of detailed information.

Diamond Drilling (DDH)

Diamond drilling of HQ diameter (TT_005DD) was completed to 137.7m recently in the completed program and was located 5m away from a RC hole already drilled (TT_003RC).

Reverse Circulation ('RC') Drilling

RC drilling at Fence Gossan was used to obtain a representative sample by means of riffle splitting with samples submitted for analysis using the above-mentioned methodologies.

Four (4) reverse circulation (RC) holes for a total of 516m have been completed at the Fence Gossan Prospect.

Four (4) RC holes were completed at Reefs Tank for a total of 564m.

At Tors Tank, four (4) RC holes for a total of 625.7m (including the cored hole) were completed.

The RC drilling technique was used to obtain a representative sample by means of a cone or riffle splitter with samples submitted for assay by mixed acid digestion and analysis via ICP-MS + ICP-AES with anticipated reporting a suite of 48 elements (sulphur >10% by LECO).

Drilling techniques

Drill type (e.g., core, reverse circulation, open-hole hammer, rotary air blast, auger, Bangka, sonic, etc.) and details (e.g. core diameter, triple or standard tube, depth of diamond tails, face-sampling bit or other type, whether core is oriented and if so, by what method, etc.).

Historical drilling consisted of auger, rotary air blast, reverse circulation, and NQ, BQ, and HQ diamond coring.  One cored hole of HQ (61mm) diameter was completed at Tors Tank after all the RC holes had been completed.

Diamond drilling will be completed with standard diameter, conventional HQ and NQ with historical holes typically utilizing RC and percussion pre-collars to an average 30 metres (see Drillhole Information for further details).

Drill sample recovery

Method of recording and assessing core and chip sample recoveries and results assessed.

Measures taken to maximise sample recovery and ensure representative nature of the samples.

Whether a relationship exists between sample recovery and grade and whether sample bias may have occurred due to preferential loss/gain of fine/coarse material.

Reverse Circulation ('RC') Drilling - Reverse circulation sample recoveries were visually estimated during drilling programs. Where the estimated sample recovery was below 100% this was recorded in field logs by means of qualitative observation.

Reverse circulation drilling employed sufficient air (using a compressor and booster) to maximise sample recovery.

Historical cored drillholes by North Broken Hill, CRA , and Pasminco were well documented and generally have >90% core recovery.

No relationship between sample recovery and grade has been observed.

Logging

Whether core and chip samples have been geologically and geotechnically logged to a level of detail to support appropriate Mineral Resource estimation, mining studies and metallurgical studies.

Whether logging is qualitative or quantitative in nature. Core (or costean, channel, etc) photography.

The total length and percentage of the relevant intersections logged.

The drilling that did occur was completed to modern-day standards. The preferred exploration strategy in the eighties and early nineties was to drill shallow auger holes to negate the influence of any Quaternary and Tertiary sedimentary cover, and then return to sites where anomalous Cu or Zn were assayed.  In this program at all three areas holes were completed to varying depths ranging from 100-160m.

No downhole geophysical logging took place; however, measurements of magnetic susceptibility were taken at the same 1m intervals as the PXRF readings were taken.

Sub-sampling techniques and sample preparation

If core, whether cut or sawn and whether quarter, half or all core taken.

If non-core, whether riffled, tube sampled, rotary split, etc and whether sampled wet or dry.

For all sample types, the nature, quality, and appropriateness of the sample preparation technique.

Quality control procedures adopted for all sub-sampling stages to maximise representivity of samples.

Measures taken to ensure that the sampling is representative of the in-situ material collected, including for instance results for field duplicate/second-half sampling.

Whether sample sizes are appropriate to the grain size of the material being sampled.

Core samples will be hand-split or sawn with re-logging of available historical core indicating a 70:30 (retained: assayed) split was typical. The variation of sample ratios noted are considered consistent with the sub-sampling technique (hand-splitting).

No second half samples will be submitted for analysis, but duplicates have been taken at a frequency of 1:20 in samples collected.

It is considered water planned to be used for core cutting is unprocessed and unlikely to have introduced sample contamination.

Procedures relating to the definition of the line of cutting or splitting are not available.  It is expected that 'standard industry practice' for the period was applied to maximize sample representivity.

Quarter core will be submitted to ALS for chemical analysis using industry standard sample preparation and analytical techniques.

The sample interval details and grades quoted for cored intervals described in various maps in the main section are given in previous ASX releases (Castillo Copper 2022a, b, c, d, e, f).

Quality of assay data and laboratory tests

The nature, quality and appropriateness of the assaying and laboratory procedures used and whether the technique is considered partial or total.

For geophysical tools, spectrometers, handheld XRF instruments, etc, the parameters used in determining the analysis including instrument make and model, reading times, calibrations factors applied and their derivation, etc.

Nature of quality control procedures adopted (eg standards, blanks, duplicates, external laboratory checks) and whether acceptable levels of accuracy (i.e. lack of bias) and precision have been established.

 

The following rare earth elements were analysed using ME-MS61R Sample Decomposition is by HF-HNO3-HClO4 acid digestion, HCl leach (GEO-4A01).  The Analytical Method for

 

Silver is shown below:

Element

Symbol

Units

Lower Limit

Upper Limit

Silver

Ag

ppm

0.01

100

Inductively Coupled Plasma - Atomic Emission Spectroscopy (ICP - AES) Inductively Coupled Plasma - Mass Spectrometry (ICP-MS)

A prepared sample (0.25 g) is digested with perchloric, nitric, hydrofluoric, and hydrochloric acids. The residue is topped up with dilute hydrochloric acid and analysed by inductively coupled plasma atomic emission spectrometry. Following this analysis, the results are reviewed for high concentrations of bismuth, mercury, molybdenum, silver, and tungsten and diluted accordingly.

Samples meeting this criterion are then analysed by inductively coupled plasma-mass spectrometry. Results are corrected for spectral interelement interferences.

Four acid digestions can dissolve most minerals: however, although the term "near total" is used, depending on the sample matrix, not all elements are quantitatively extracted.

Results for the additional rare earth elements will represent the acid leachable portion of the rare earth elements and as such, cannot be used, for instance to do a chondrite plot.

Geochemical Procedure

Element geochemical procedure reporting units and limits are listed below:

Element

Symbol

Units

Lower Limit

Upper Limit

Molybdenum

Mo

ppm

0.05

10 000

Sodium

Na

%

0.01

10

Niobium

Nb

ppm

0.1

500

Nickel

Ni

ppm

0.2

10 000

Phosphorous

P

ppm

10

10 000

Lead

Pb

ppm

0.5

10 000

Rubidium

Rb

ppm

0.1

10 000

Rhenium

Re

ppm

0.002

50

Sulphur

S

%

0.01

10

Antimony

Sb

ppm

0.05

10 000

Scandium

Sc

ppm

0.1

10 000

Selenium

Se

ppm

1

1 000

Tin

Sn

ppm

0.2

500

Strontium

Sr

ppm

0.2

10 000

Tantalum

Ta

ppm

0.05

100

Tellurium

Te

ppm

0.05

500

Thorium

Th

ppm

0.2

10 000

Titanium

Ti

%

0.005

10

Thallium

Tl

ppm

0.02

10 000

Uranium

U

ppm

0.1

10 000

Vanadium

V

ppm

1

10 000

Tungsten

W

ppm

0.1

10 000

 

Element

Symbol

Units

Lower Limit

Upper Limit

Yttrium

Y

ppm

0.1

500

Zinc

Zn

ppm

2

10 000

Zirconium

Zr

ppm

0.5

500

Dysprosium

Dy

ppm

0.05

1 000

Erbium

Er

ppm

0.03

1 000

Europium

Eu

ppm

0.03

1 000

Gadolinium

Gd

ppm

0.05

1 000

Holmium

Ho

ppm

0.01

1 000

Lutetium

Lu

ppm

0.01

1 000

Neodymium

Nd

ppm

0.1

1 000

Praseodymium

Pr

ppm

0.03

1 000

Samarium

Sm

ppm

0.03

1 000

Terbium

Tb

ppm

0.01

1 000

Thulium

Tm

ppm

0.01

1 000

Ytterbium

Yb

ppm

0.03

1 000

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Element

Symbol

Units

Lower Limit

Upper Limit

Aluminum

Al

%

0.01

50

Arsenic

As

ppm

0.2

10 000

Barium

Ba

ppm

10

10 000

Beryllium

Be

ppm

0.05

1 000

Bismuth

Bi

ppm

0.01

10 000

Calcium

Ca

%

0.01

50

Cadmium

Cd

ppm

0.02

1 000

Cerium

Ce

ppm

0.01

500

Cobalt

Co

ppm

0.1

10 000

Chromium

Cr

ppm

1

10 000

Cesium

Cs

ppm

0.05

500

Copper

Cu

ppm

0.2

10 000

Iron

Fe

%

0.01

50

Gallium

Ga

ppm

0.05

10 000

Germanium

Ge

ppm

0.05

500

Hafnium

Hf

ppm

0.1

500

Indium

In

ppm

0.005

500

Potassium

K

%

0.01

10

Lanthanum

La

ppm

0.5

10 000

Lithium

Li

ppm

0.2

10 000

Magnesium

Mg

%

0.01

50

Manganese

Mn

ppm

5

100 000

Laboratory inserted standards, blanks and duplicates were analysed per industry standard practice.  There was no evidence of bias from these results.

Verification of sampling and assaying

The verification of significant intersections by either independent or alternative company personnel.

The use of twinned holes.

Documentation of primary data, data entry procedures, data verification, data storage (physical and electronic) protocols.

Discuss any adjustment to assay data.

· None of the drillholes have been twinned, as they are historical holes.

· Conversion of elemental analysis (REE parts per million) to stoichiometric oxide (REO parts per million) was undertaken by ROM geological staff using the below (Table D1-1) element to stoichiometric oxide conversion factors ( https://www.jcu.edu.au/news/releases/2020/march/rare-earth-metals-an-untapped-resource )

 

Table D1-1:  Element -Conversion Factor -Oxide Form

Ce

1.2284

  CeO2

Dy

1.1477

  Dy2O3

Er

1.1435

  Er2O3

Eu

1.1579

  Eu2O3

Gd

1.1526

  Gd2O3

Ho

1.1455

  Ho2O3

La

1.1728

  La2O3

Lu

1.1371

  Lu2O3

Nd

1.1664

  Nd2O3

Pr

1.2083

  Pr6O11

Sm

1.1596

  Sm2O3

Tb

1.1762

  Tb4O7

Tm

1.1421

Tm2O3

Y

1.2699

Y2O3

Yb

1.1387

Yb2O3

 

 

 

 

Rare earth oxide is the industry accepted form for reporting rare earths. The following calculations are used for compiling REO into their reporting and evaluation groups:

TREO (Total Rare Earth Oxide) = La2O3 + CeO2 + Pr6O11 + Nd2O3 + Sm2O3 + Eu2O3 + Gd2O3 + Tb4O7 + Dy2O3 + Ho2O3 + Er2O3 + Tm2O3 + Yb2O3 + Y2O3 + Lu2O3.

TREO-Ce = TREO - CeO2

LREO (Light Rare Earth Oxide) = La2O3 + CeO2 + Pr6O11 + Nd2O3 + Sm2O3 

HREO (Heavy Rare Earth Oxide) = Eu2O3 + Gd2O3 + Tb4O7 + Dy2O3 + Ho2O3 + Er2O3 + Tm2O3 + Yb2O3 + Y2O3 + Lu2O3

CREO (Critical Rare Earth Oxide) = Nd2O3 + Eu2O3 + Tb4O7 + Dy2O3 + Y2O3

MREO (Magnetic Rare Earth Oxide) = Pr6O11 + Nd2O3 + Sm2O3 + Gd2O3 + Tb4O7 + Dy2O3.

Total Rare Earth Oxides (TREO):

To calculate TREO an oxide conversion "factor" is applied to each rare-earth element assay.  The "factor" equates an elemental assay to an oxide concentration for each element. Below is an example of the factor calculation for Lanthanum (La):

Relative Atomic Mass (La) = 138.9055

Relative Atomic Mass (O) = 15.9994

Oxide Formula = La2O3

Oxide Conversion Factor = 1/ ((2x 138.9055)/(2x 138.9055 + 3x 15.9994)) Oxide Conversion Factor = 1.173 (3dp)

None of the historical data has been adjusted.

Location of data points

Accuracy and quality of surveys used to locate drill holes (collar and down-hole surveys), trenches, mine workings and other locations used in Mineral Resource estimation.

Specification of the grid system used.

Quality and adequacy of topographic control.

In general, locational accuracy does vary, depending upon whether the historical surface and drillhole samples were digitised off plans or had their coordinated tabulated.  Many samples were originally reported to AGD66 or AMG84 and have been converted to MGA94 (Zone 54)

The holes are currently surveyed with handheld GPS, awaiting more accurate DGPS survey.  It is thus estimated that locational accuracy therefore varies between 2-4m until the more accurate surveying is completed.  This assessment was confirmed once the holes were surveyed by DGPS from GMC Surveying.

The quality of topographic control (GSNSW 1 sec DEM) is deemed adequate for the purposes of the exploration drilling program.

Data spacing and distribution

Data spacing for reporting of Exploration Results.

Whether the data spacing and distribution is sufficient to establish the degree of geological and grade continuity appropriate for the Mineral Resource and Ore Reserve estimation procedure(s) and classifications applied.

Whether sample compositing has been applied.

The average sample spacing from the current drilling program across the tenure varies per prospect, and sample type, as listed in Table D1-2, below:

Table D1-2:  EL 8434 Drillhole Spacing

Prospect

Drillholes Completed

RMS Drillhole Spacing (m)

The Sisters

Not yet


Iron Blow

Not Yet


Tors Tank

4

127

Fence Gossan

4

208

Ziggy's Hill

n/a

n/a

Reefs Tank

1


The Datamine software allows creation of fixed length samples from the original database given a set of stringent rules.

Orientation of data in relation to geological structure

Whether the orientation of sampling achieves unbiased sampling of possible structures and the extent to which this is known, considering the deposit type.

If the relationship between the drilling orientation and the orientation of key mineralised structures is considered to have introduced a sampling bias, this should be assessed and reported if material.

Historical drill holes at the BHAE are typically drilled vertically for auger and RAB types (drilled along section lines) and angled at -55˚ or -60˚ to the horizontal and drilled perpendicular to the mineralised trend for RC and DDH (Figure D1-3 and D1-4).

Drilling orientations are adjusted along strike to accommodate folded geological sequences.  All Fence Gossan holes were designed to drill toward grid south at an inclination of 60 degrees from horizontal.

The drilling orientation is not considered to have introduced a sampling bias on assessment of the current geological interpretation.

Geological mapping by various companies has reinforced that the strata dips variously between 5 and 65 degrees.

Sample security

The measures taken to ensure sample security.

Sample security procedures are considered 'industry standard' for the current period.

Samples obtained during drilling completed between 4/10/22 to the 10/10/22 were transported by exploration employees or an independent courier directly from Broken Hill to ALS Laboratory, Adelaide.

The Company considers that risks associated with sample security are limited given the nature of the targeted mineralisation.

Audits or reviews

The results of any audits or reviews of sampling techniques and data.

No external audits or reviews have yet been undertaken.

 

SECTION 2: REPORTING OF EXPLORATION RESULTS

Criteria

JORC Code explanation

Commentary

Mineral tenement and land tenure status

Type, reference name/number, location and ownership including agreements or material issues with third parties such as joint ventures, partnerships, overriding royalties, native title interests, historical sites, wilderness or national park and environmental settings.

The security of the tenure held at the time of reporting along with any known impediments to obtaining a licence to operate in the area.

EL 8434 is located about 28km east of Broken Hill whilst EL 8435 is 16km east of Broken Hill.  Both tenures are approximately 900km northwest of Sydney in far western New South Wales (Figures D2-1 and D2-2 in Appendix A &B, above). 

EL 8434 and EL 8435 were both granted on the 2nd of June 2016 to Squadron Resources for a term of five (5) years for Group One Minerals.  On the 25th of May 2020, Squadron Resources changed its name to Wyloo Metals Pty Ltd (Wyloo).  In December 2020 the tenure was transferred from Wyloo Metals to Broken Hill Alliance Pty Ltd a 100% subsidiary company of Castillo Copper Limited.  Both tenures were renewed on the 12th of August 2021 for a further six (6) years and are due to expire on the 2nd of June 2027.

EL 8434 lies across two (2) 1:100,000 geology map sheets Redan 7233 and Taltingan 7234, and two (2) 1:250,000 geology map sheets, SI54-3 Menindee, and SH54-15 Broken Hill in the county of Yancowinna.  EL 8434 consists of one hundred and eighty-six (186) units) in the Adelaide and Broken Hill 1:1,000,000 Blocks covering an area of approximately 580km2.

EL 8435 is located on the 1:100,000 geology map sheet Taltingan 7234, and the 1:250,000 geology map sheet SH/54-15 Broken Hill in the county of Yancowinna.  EL 8435 consists of twenty-two (22) units (Table 1) in the Broken Hill 1:1,000,000 Blocks covering an area of approximately 68km2.

Access to the tenures from Broken Hill is via the sealed Barrier Highway.  This road runs north-east to south-west through the northern portion of the EL 8434, passes the southern tip of EL 8435 eastern section and through the middle of the western section of EL 8435.  Access is also available via the Menindee Road which runs north-west to south-east through the southern section of the EL 8434.  The Orange to Broken Hill Rail line also dissects EL 8435 western section the middle and then travels north-west to south-east slicing through the eastern arm of EL 8434 (Figure D2-1).

Figure D2-1:  EL 8434 and EL 8435 General Location Map

Exploration done by other parties

Acknowledgment and appraisal of exploration by other parties.

Explorers who were actively involved over longer historical periods in various parts of EL8434 were: - North Broken Hill Ltd, CRAE Exploration, Major Mining Ltd and Broken Hill Metals NL, Pasminco Exploration Ltd, Normandy Exploration Ltd, PlatSearch NL/Inco Ltd/ EGC Pty Ltd JV and the Western Plains Gold Ltd/PlatSearch/EGC Pty Ltd JV.

A comprehensive summary of work by previous explorers was presented in Leyh (2009). However, more recently, follow-up field reconnaissance of areas of geological interest, including most of the prospective zones was carried out by EGC Pty Ltd over the various licenses. This work, in conjunction with a detailed interpretation of aeromagnetic, gravity plus RAB / RC drill hole logging originally led to the identification of at least sixteen higher priority prospect areas. All these prospects were summarized in considerable detail in Leyh (2008).  Future work programs were then also proposed for each area.  Since then, further compilation work plus detailed geological reconnaissance mapping and sampling of gossans and lode rocks has been carried out.

A total of 22 prospects were then recognised on the exploration licence with at least 12 occurring in and around the tenure.

With less than 45% outcropping Proterozoic terrain within the licence, this makes it very difficult to explore and is in the main very effectively screened from the easy application of more conventional exploration methodologies due to a predominance of extensive Cainozoic cover sequences.  These include recent to young Quaternary soils, sands, clays and older more resistant, only partially dissected, Tertiary duricrust regolith covered areas.  Depth of cover ranges from a few metres in the north to over 60 metres in some areas on the southern and central license.

Exploration by EGC Pty Ltd carried out in the field in the first instance has therefore been heavily reliant upon time consuming systematic geological reconnaissance mapping and relatable geochemical sampling. These involve a slow systematic search over low outcropping areas, poorly exposed subcrops and float areas as well as the progressive development of effective regolith mapping and sampling tools.  This work has been combined with a vast amount of intermittently acquired past exploration data.  The recent data compilation includes an insufficiently detailed NSWGS regional mapping scale given the problems involved, plus some regionally extensive, highly variable, low-level stream and soil BLEG geochemical data sets over much of the area. 

There are also a few useful local detailed mapping grids at the higher priority prospects, and many more numerous widespread regional augers, RAB, and percussion grid drilling data sets. Geophysical data sets including ground magnetics, IP and EM over some prospect areas have also been integrated into the exploration models.  These are located mainly in former areas of moderate interest and most of the electrical survey methods to date in this type of terrain continue to be of limited application due to the high degree of weathering and the often prevailing and complex regolith cover constraints.

Between 2007 and 2014 Eaglehawk Geological Consulting has carried out detailed research, plus compilation and interpretation of a very large volume of historic exploration data sourced from numerous previous explorers and dating back to the early 1970's. Most of this data is in non-digital scanned form. Many hard copy exploration reports (see references) plus several hundred plans have been acquired from various sources, hard copy printed as well as downloaded as scans from the Geological Survey of NSW DIGS system. They also conducted field mapping, costean mapping and sampling, and rock chip sampling and analysis.

Work Carried out by Squadron Resources and Whyloo Metals 2016-2020

Research during Year 1 by Squadron Resources revealed that the PGE-rich, sulphide-bearing ultramafic rocks in the Broken Hill region have a demonstrably alkaline affinity.  This indicates a poor prospectivity for economic accumulations of sulphide on an empirical basis (e.g., in comparison to all known economic magmatic nickel sulphide deposits, which have a dominantly tholeiitic affinity).  Squadron instead directed efforts toward detecting new Broken Hill-Type (BHT) deposits that are synchronous with basin formation.  Supporting this modified exploration rationale are the EL's stratigraphic position, proximity to the Broken Hill line of lode, abundant mapped alteration (e.g., gahnite and/or garnet bearing exhalative units) and known occurrences such as the "Sisters" and "Iron Blow" prospects.

The area overlies a potential magmatic Ni-Cu-PGE source region of metasomatised sub-continental lithospheric mantle (SCLM) identified from a regional targeting geophysical data base.  The exploration model at the time proposed involved remobilization of Ni-Cu-PGE in SCLM and incorporation into low degree mafic-ultramafic partial melts during a post-Paleoproterozoic plume event and emplacement higher in the crust as chonoliths/small intrusives - Voisey's Bay type model.  Programs were devised to use geophysics and geological mapping to locate secondary structures likely to control and localise emplacement of Ni-Cu-PGE bearing chonoliths. Since EL8434 was granted, the following has been completed:

Airborne EM survey.

Soil and chip sampling.

Data compilation.

Geological and logistical reconnaissance.

Community consultations; and

Execution of land access agreements.

Airborne EM Survey

Geotech Airborne Limited was engaged to conduct an airborne EM survey using their proprietary VTEM system in 2017.  A total of 648.92-line kilometres were flown on a nominal 200m line spacing over a portion of the project area. Several areas were infilled to 100m line spacing.

The VTEM data was interpreted by Southern Geoscience Consultants Pty Ltd, who identified a series of anomalies, which were classified as high or low priority based on anomaly strength (i.e., does the anomaly persist into the latest channels).  Additionally, a cluster of VTEM anomalies at the "Sisters" prospect have been classified separate due to strong IP effects observed in the data.  Geotech Airborne have provided an IP corrected data and interpretation of the data has since been undertaken.

Soil and Chip sampling

The VTEM anomalies were followed up by a reconnaissance soil sampling programme. Spatially clustered VTEM anomalies were grouped, and follow-up soil lines were designed.  Two (2) VTEM anomalies were found to be related to culture and consequently no soils were collected.  Two (2) other anomalies were sampled which were located above thick alluvium of Stephens Creek and were therefore not sampled.  A line of soil samples was collected over a relatively undisturbed section at Iron Blow workings and the Sisters Prospect.

One hundred and sixty-six (166) soil samples were collected at a nominal 20cm depth using a 2mm aluminum sieve.  Two (2) rock chips were also collected during this program.  The samples were collected at either 20m or 40m spacing over selected VTEM anomalies.  The samples were pulverised and analysed by portal XRF at ALS laboratories in Perth.

Each site was annotated with a "Regolith Regime" such that samples from a depositional environment could be distinguished from those on exposed Proterozoic bedrock, which were classified as an erosional environment.  The Regolith Regime groups were used for statistical analysis and levelling of the results.  The levelled data reveals strong relative anomalies in zinc at VTEM anomaly clusters 10, 12 and 14 plus strong anomalous copper at VTEM 17.

Geology

Deposit type, geological setting, and style of mineralisation.

As the strata is tightly folded, the intersected cobalt-rich layers are overstated in terms of apparent thickness, however the modelling software calculates a true, vertical thickness.  Cobalt mineralisation is commonly associated with shears, faults, amphibolites, and a quartz-magnetite rock within the shears, or on or adjacent to the boundaries of the Himalaya Formation. In general, most of the cobalt and rare earth element - rich layers have a north-northwest to north strike.

REE enrichment generally occurs as a 5 to 10-metre-thick zone between the completely weathered layer and strongly weathered layer and it is targeted for commercial mining (Figure D2-2).  Compared to other REE deposits, regolith-hosted rare earth element deposits are substantially low-moderate grade (containing 0.05-0.3 wt.% extractable REEs).  Nevertheless, due to its easy extraction method, low processing costs and large abundance, the orebodies are generally economic to be extracted ( Duuring, (2020); Kanazawa and Kamitani (2006); and Murakami, H.; Ishihara (2008) ).

Figure D2-2: Weathering Profile over REE - Rich Granite

A picture containing chart Description automatically generated

https://en.wikipedia.org/wiki/Regolith-hosted_rare_earth_element_deposits

Weathering profile of regolith hosted REE deposits shown above, the legend is: (A) Humic layer. (B) Completely weathered layer. (C) Strongly weathered layer. (D) Weathering front. (E) Unweathered rock.

Most of the REE found in cerium monazite (Ce (PO4)) which always contains major to minor amounts of other REE (Nd, La, Pr, Sm etc) replacing Ce.  Also, the mineral often contains trace amounts of U and Th (coupled with Ca).  This will be collaborated with XRD and or SEM analysis. 

Drill hole Information

A summary of all information material to the understanding of the exploration results including a tabulation of the following information for all Material drill holes:

easting and northing of the drill hole collar

elevation or RL (Reduced Level - elevation above sea level in metres) of the drill hole collar

dip and azimuth of the hole

down hole length and interception depth

hole length.

If the exclusion of this information is justified on the basis that the information is not Material and this exclusion does not detract from the understanding of the report, the Competent Person should clearly explain why this is the case.

Header information about all drillholes completed at Reefs Tank, Tors Tank and Fence Gossan have been tabulated in this release in Appendix C.

Data aggregation methods

In reporting Exploration Results, weighting averaging techniques, maximum and/or minimum grade truncations (e.g., cutting of high grades) and cut-off grades are usually Material and should be stated.

Where aggregate intercepts incorporate short lengths of high-grade results and longer lengths of low-grade results, the procedure used for such aggregation should be stated and some typical examples of such aggregations should be shown in detail.

The assumptions used for any reporting of metal equivalent values should be clearly stated.

No metal equivalents have been reported.  Rare earth element results have been converted to rare earth oxides as per standard industry practice (Castillo Copper 2022f).

No compositing of assay results has taken place, but rather menu options within the Datamine GDB module have been used to create fixed length 1m assay intervals from the original sampling lengths.

The rules follow very similarly to those used by the Leapfrog Geo software in creating fixed length samples.

Relationship between mineralisation widths and intercept lengths

These relationships are particularly important in the reporting of Exploration Results.

If the geometry of the mineralisation with respect to the drill hole angle is known, its nature should be reported.

If it is not known and only the down hole lengths are reported, there should be a clear statement to this effect (e.g., 'down hole length, true width not known').

A database of all the historical borehole sampling has been compiled and validated. It is uncertain if there is a strong relationship between the surface sample anomalies to any subsurface anomalous intersections due to the possible masking by variable Quaternary and Tertiary overburden that varies in depth from 0-15m.  The mineralisation appears to be secondary enrichment in the regolith clays and extremely weathered material derived from quartzo-feldspathic pegmatites.  

Diagrams

Appropriate maps and sections (with scales) and tabulations of intercepts should be included for any significant discovery being reported These should include, but not be limited to a plan view of drill hole collar locations and appropriate sectional views.

Current surface anomalies are shown on maps released on the ASX (Castillo Copper 2022d, 2022e, 2022f and 2022g).  All historical surface sampling has had their coordinates converted to MGA94, Zone 54.

Balanced reporting

Where comprehensive reporting of all Exploration Results is not practicable, representative reporting of both low and high grades and/or widths should be practiced to avoid misleading reporting of Exploration Results.

All recent laboratory analytical results have been recently reported (see Castillo Copper 2022a, b, c, d, e, f, and g) for assay results.

Regarding the surface and sampling, no results other than duplicates, blanks or reference standard assays have been omitted.

Other substantive exploration data

Other exploration data, if meaningful and material, should be reported including (but not limited to): geological observations; geophysical survey results; geochemical survey results; bulk samples - size and method of treatment; metallurgical test results; bulk density, groundwater, geotechnical and rock characteristics; potential deleterious or contaminating substances.

Historical explorers have also conducted airborne and ground gravity, magnetic, EM, and IP resistivity surveys over parts of the tenure area but this is yet to be fully georeferenced (especially the ground IP surveys). Squadron Resources conducted an airborne EM survey in 2017 that covers Iron Blow and The Sisters, but not the southern cobalt and REE prospects.

REFERENCES

Biggs, M. S., 2021a, Broken Hill Alliance, NSW Tenure Package Background Geological Information, unpublished report to BH Alliance Pty Ltd, Sep 21, 30pp.

Biggs, M. S., 2021b, EL 8434 and EL 8435, Brief Review of Surface Sample Anomalies Lithium, Rare Earth Elements and Cobalt, unpublished report to BH Alliance Pty Ltd, Nov 21, 18pp.

Biggs, M.S., 2022a, BHA Cobalt Modelling and Mineral Resource Estimate Update, unpublished memo for Castillo Copper by ROM Resources.

Biggs, M.S., 2022b, Broken Hill BHA Tenures Update, Castillo Copper, unpublished memo prepared by ROM Resources, Mar 22, 5pp

Biggs M.S., 2022c, Geological Briefing Paper, Iron Blow Prospect, East Zone, BHA Project (BHAE), Broken Hill, NSW, ROM Resources, prepared for Castillo Copper Limited, August 2022

Burkett R.D., 1975, Progress Report on Exploration Licenses 780, 781, 782 and 783, Broken Hill Area, NSW for the six months to 23rd November 1975, North Broken Hill Limited for the NSW Geological Survey, (GS1975-328)

Castillo Copper Limited, 2020, ASX Release Acquisition enhances BHT (zinc-silver-lead) and IOCG (gold-copper) prospectivity at Broken Hill, 1st October 2020.

Castillo Copper Limited, 2022a, ASX Release Battery metal drill-hole assays unlock BHA East Zone potential / lithium update, 5th January 2022.

Castillo Copper Limited, 2022b, ASX Release Strategic focus to develop significant cobalt mineralisation potential at BHA Project, 9th February 2022.

Castillo Copper Limited, 2022c, ASX Release High grade platinum confirmed at BHA Project, 9th March 2022.

Castillo Copper Limited, 2022d ASX Release Diamond core tests demonstrate high-grade cobalt-zinc potential at Broken Hill, 21 March 2022

Castillo Copper Limited, 2022e ASX Release, Drilling hits targeted cobalt zones & wide pegmatite intercepts at Broken Hill 12 October 2022

Castillo Copper Limited, 2022f ASX Release, Drilling hits more wide pegmatite intercepts at Broken Hill, 24 October 2022

Castillo Copper Limited, 2022g ASX Release, Completed auger sampling campaign targets 6.5km2 REE mineralisation zone, 23 December 2022

Duuring, P 2020, Rare-element pegmatites: a mineral systems analysis: Geological Survey of Western Australia, Record 2020/7, 6p.

Kanazawa, Y.; Kamitani, M., 2006, "Rare earth minerals and resources in the world". Journal of Alloys and Compounds. 408: 1339-1343. doi:10.1016/j.jallcom.2005.04.033

Lees, T.C., 1978, Progress Report on Farmcote Exploration Licenses 780 and 782, Farmcote Area, Broken Hill, NSW for the six months to 23RD November 1978, North Broken Hill Limited for the NSW Geological Survey, (GS1978-043)

Leyh, W.R., 1976, Progress Report on Exploration Licence, No. 846 Iron Blow -Yellowstone Area, Broken Hill, New South Wales for the six months period ended 29th June 1976, North Broken Hill Limited, Report GS1976-198, Jul 76, 88pp

Leyh, W.R., 1977a, Progress Report on Exploration Licence, No. 846 Iron Blow -Yellowstone Area, Broken Hill, New South Wales for the six months period ended 29th December 1976, North Broken Hill Limited, Report GS1976-198, Feb 1977, 24pp

Leyh W.R., 1977b, Progress Report on Farmcote Exploration Licenses 780 and 782, Farmcote Area, Broken Hill, NSW for the three months to 5th March 1977, North Broken Hill Limited for the NSW Geological Survey, (GS1977-078)

Leyh W.R., 1977c, Progress Report on Farmcote Exploration Licenses 780 and 782, Farmcote Area, Broken Hill, NSW for the three months to 23rd May 1977, North Broken Hill Limited for the NSW Geological Survey, (GS1977-078)

Leyh W.R., 1978, Progress Report on Farmcote Exploration Licenses 780 and 782, Farmcote Area, Broken Hill, NSW for the three months to 27 October 1978, North Broken Hill Limited for the NSW Geological Survey, (GS1977-078)

Leyh W.R., 1978 Progress Report on Exploration Licenses 1099 and 1100 for the six months to 27 October 1978, North Broken Hill Limited for the NSW Geological Survey, (GS1978-407)

Leyh, W.R., 1990, Exploration Report for the Third Six Monthly Period ended 12th June 1990 for EL 3238 (K Tank), Broken Hill District, New South Wales for the six months period, Pasminco Limited, Report GS1989-226, Jun 90, 22pp

Leyh, W.R., and Lees T.C., 1977, Progress Report on Exploration Licence, No. 846 Iron Blow -Yellowstone Area, Broken Hill, New South Wales for the six months period ended 29th June 1977, North Broken Hill Limited, Report GS1976-198, Jul 77, 35pp

Leyh, W.R., and Larson P.D., 1981, Final Report for the Third Six Monthly Period ended 12th June 1990 for EL 3238 (K Tank), Broken Hill District, New South Wales for the six months period, Pasminco Limited, Report GS1989-226, Jun 90, 22pp

McConachie, G.W., 1997, EL 4792 Redan, Annual Report for the period ending 19/2/1997, Normandy Exploration Limited, unpublished report to the GSNSW, RIN 00002672

Main, J.V., and Tucker D.F., 1981, Exploration Report for Six Month Period 8th November 1980 to 7th May 1981, EL 1106 Rockwell, Broken Hill, NSW, CRA Exploration Pty Ltd, GS1980-080, Jul 1981, 40pp

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https://en.wikipedia.org/wiki/Regolith-hosted_rare_earth_element_deposits

Murakami, H.; Ishihara, S., 2008, REE mineralization of weathered crust and clay sediment on granitic rocks in the Sanyo Belt, SW Japan and the Southern Jiangxi Province, China". Resource Geology. 58 (4): 373-401. doi:10.1111/j.1751-3928.2008.00071.x.

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Willis, I.L., Brown, R.E., Stroud, W.J., Stevens, B.P.J., 1983, The Early Proterozoic Willyama Supergroup: stratigraphic subdivision and interpretation of high to low-grade metamorphic rocks in the Broken Hill Block, New South Wales., Geological Society of Australia Journal, 30(2), p195-2

Further work

The nature and scale of planned further work (e.g., tests for lateral extensions or depth extensions or large-scale step-out drilling).

Diagrams clearly highlighting the areas of possible extensions, including the main geological interpretations and future drilling areas, provided this information is not commercially sensitive.

It is recommended that:

· The remaining non-sampled zones within the Core Library drillholes, BH1, BH2, and DD90-IB3 in the north of the tenure group be relogged and sampled.  DD90-IB3 had 21-87m retested recently and is a good candidate for hyperspectral logging.

· A program of field mapping and ground magnetic, IP or radiometric surveys be planned and executed at Fence Gossan.  Mapping of pegmatite outcrops is a high priority.

· Complete rehabilitation of the 2022 BHAE drilling campaign that comprised mostly RC drilling.  An application supporting an ESF2 lodgment is yet to be approved by the NSW Resource Regulator

· Depending upon the results of the proposed geophysical surveys above, the next drilling program will specifically target the air coring technique over the known cobalt and REE mineralisation downdip to at least 30m depth at all three prospects.  That proposed drilling program is also designed to increase the resource confidence of the REE to an Exploration target or Inferred Resources to the standard of the 2012 JORC Code.

 

 

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